Ce-hydroxamate metal-organic frameworks for photocatalytic H generation

Exploring the rich coordination chemistry of Ce, here we report two new entries in the emerging category of hydroxamate-based metal-organic frameworks (MOFs). The two Ce-hydroxamate MOFs exhibited different band structures and photoelectrochemical properties based on their respective coordinative en...

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Published in:Chemical communications (Cambridge, England) England), 2022-12, Vol.58 (97), p.1353-1356
Main Authors: Feng, Xuan, Li, Wenying, Yang, Lei, Song, Ting, Xia, Zhaoming, Lai, Qiuxue, Zhou, Xuemei, Xiao, Hai, Liu, Chong
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container_issue 97
container_start_page 1353
container_title Chemical communications (Cambridge, England)
container_volume 58
creator Feng, Xuan
Li, Wenying
Yang, Lei
Song, Ting
Xia, Zhaoming
Lai, Qiuxue
Zhou, Xuemei
Xiao, Hai
Liu, Chong
description Exploring the rich coordination chemistry of Ce, here we report two new entries in the emerging category of hydroxamate-based metal-organic frameworks (MOFs). The two Ce-hydroxamate MOFs exhibited different band structures and photoelectrochemical properties based on their respective coordinative environments and overall structures, leading to varied H 2 generation performances. Exploring the rich coordination chemistry of cerium, two new hydroxamate MOFs are reported, featuring distinct band structures and photoelectrochemical properties for H 2 generation.
doi_str_mv 10.1039/d2cc05189c
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title Ce-hydroxamate metal-organic frameworks for photocatalytic H generation
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