A porous Ti-based metal-organic framework for CO photoreduction and imidazole-dependent anhydrous proton conduction

The anhydrous proton conductivity of Im@IEF-11 resulting from the integration of imidazole and porous IEF-11 has been investigated, and the highest proton conductive value can reach up to 7.64 × 10 −2 S cm −1 . Furthermore, IEF-11 is also developed to reduce CO 2 due to its reasonable structure and...

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Published in:Chemical communications (Cambridge, England) England), 2023-01, Vol.59 (8), p.17-173
Main Authors: Qu, Jian-Xin, Fu, Yao-Mei, Meng, Xing, He, Yu-Ou, Sun, Hong-Xu, Yang, Rui-gang, Wang, Hai-Ning, Su, Zhong-Min
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Summary:The anhydrous proton conductivity of Im@IEF-11 resulting from the integration of imidazole and porous IEF-11 has been investigated, and the highest proton conductive value can reach up to 7.64 × 10 −2 S cm −1 . Furthermore, IEF-11 is also developed to reduce CO 2 due to its reasonable structure and suitable energy band, and its CO formation rate is 31.86 μmol g −1 h −1 . A porous metal-organic framework for imidazole-dependent anhydrous proton conduction and photocatalytic CO 2 reduction.
ISSN:1359-7345
1364-548X
DOI:10.1039/d2cc06214c