Sb-Doped metallic 1T-MoS nanosheets embedded in N-doped carbon as high-performance anode materials for half/full sodium/potassium-ion batteries

• Published in: Dalton transactions : an international journal of inorganic chemistry 2022-08, Vol.51 (31), p.11685-11692
• Main Authors: Liu, Yanru, Lei, Zewei, Li, Xinye, Lin, Chuyuan, Liu, Renpin, Cao, Changlin, Chen, Qinghua, Wei, Mingdeng, Zeng, Lingxing, Qian, Qingrong
• Format: Article
• ISSN: 1477-9226; 1477-9234
• DOI: 10.1039/d2dt01986h

Metal 1T phase molybdenum disulfide (1T-MoS 2 ) is being actively considered as a promising anode due to its high conductivity, which can improve electron transfer. Herein, we elaborately designed stable Sb-doped metallic 1T phase molybdenum sulfide (1T-MoS 2 -Sb) with a few-layered nanosheet structure via a simple calcination technique. The N-doping of the carbon and Sb-doping induce the formation of T-phase MoS 2 , which not only effectively enhances the entire stability of the structure, but also improves its cycling performance and stability. When employed as an anode of sodium-ion batteries (SIBs), 1T-MoS 2 -Sb exhibits a reversible capacity of 493 mA h g −1 at 0.1 A g −1 after 100 cycles and delivers prominent long-term performance (253 mA h g −1 at 1 A g −1 after 2200 cycles) along with decent rate capability. Paired with a Na 3 V 2 (PO 4 ) 3 cathode, it displays a superior capacity of 242 mA h g −1 at 0.5 A g −1 over 100 cycles, which is one of the best performances of a MoS 2 -based full cell for SIBs. Employed as the anode for potassium-ion batteries (PIBs), it exhibits a satisfactory specific capacity of 343 mA h g −1 at 0.1 A g −1 after 100 cycles. This facile strategy will provide new insights for designing T-phase advanced anode materials for SIBs/PIBs. 1T-MoS 2 -Sb composite is synthesized by a facile strategy couples with sulfuration process with the assistance of chitosan as the adsorbent. It exhibits an impressive capacity and ultra-long cycling lifespan for sodium/potassium-ion batteries.