Biphenyl-containing amido Schiff base derivative as a turn-on fluorescent chemosensor for Al and Zn ions

• Published in: New journal of chemistry 2022-08, Vol.46 (33), p.1625-1634
• Main Authors: Hoque, Anamika, Islam, Md Sanaul, Khan, Mehebub Ali, Ghosh, Soumen, Sekh, Md. Asraful, Hussain, Sahid, Alam, Md. Akhtarul
• Format: Article
• Language: English
• ISSN: 1144-0546; 1369-9261
• DOI: 10.1039/d2nj03144b

A hydrazine-derived bis(2-hydroxybenzylidene)-[1,1-biphenyl]-2,2-dicarbohydrazide (sensor 1 ) has been synthesized and its sensing properties toward metal ions have been demonstrated using simple UV-visible spectroscopy, fluorometry and visible color change techniques. The sensor 1 showed high fluorescence selectivity and sensitivity toward Al 3+ and Zn 2+ ions in aqueous DMF media. The fluorescence intensity of 1 increases in the presence of Al 3+ at 458 nm and in the presence of Zn 2+ at 478 nm. Visual color change under 350 nm UV light exhibits a bluish-white and bluish-yellow fluorescence light in the presence of Al 3+ and Zn 2+ ion, respectively. The ESI-MS and Job's plot analysis show that sensor 1 and metal ions formed a 1:2 coordination complex. A fluorescenct switch based on the control of Zn 2+ and EDTA proved that sensor 1 could act as a reversible chemosensor. However, on the addition of the EDTA into 1 -Al 3+ complex, there was no spectral change and naked-eye color change was observed. The sensing behavior was also studied with the molecular logic function of the AND gate. Furthermore, "Test Kits" coated with sensor 1 showed the successful selective detection of Al 3+ ion under UV light. A hydrazine-derived bis(2-hydroxybenzylidene)-[1,1-biphenyl]-2,2-dicarbohydrazide (sensor 1 ) can selectively recognize Al 3+ and Zn 2+ with significant fluorescence enhancement at 458 nm and 478 nm.