Boosting the OER activity of amorphous IrO in acidic medium by tuning its electron structure using lanthanum salt nanosheets

• Published in: New journal of chemistry 2023-01, Vol.47 (5), p.2619-2625
• Main Authors: Wang, Xuefeng, Jang, Haeseong, Li, Zijian, Li, Haisen, Li, Guangkai, Kim, Min Gyu, Ji, Xuqiang, Qin, Qing, Liu, Xien
• Format: Article
• ISSN: 1144-0546; 1369-9261
• DOI: 10.1039/d2nj05464g

Promoting the activity of Ir-based nanomaterials for oxygen evolution reaction (OER) in acid media without losing their durability is crucial for reducing overpotentials in energy conversion, such as electrochemical water splitting. Here, a nanocomposite composed of a-IrO x and lanthanum salt (LaCO 3 OH) was constructed to further improve its OER activity by tuning the electronic structure of a-IrO x , because a-IrO x is a well-known critical material as the active layer of Ir-based anodic catalysts. The interaction between Ir and La via O atoms as a bridge in the catalyst IrO x /LaCO 3 OH, verified by X-ray absorption near edge structure spectroscopy, tunes the electronic structure of a-IrO x and thus obviously enhances its activity for the OER in acid media, compared with commercially available IrO 2 as well as most of the reported Ir-based OER electrocatalysts. The overpotential of IrO x /LaCO 3 OH at a current density of 10 mA cm −2 is 255 mV with a Tafel slope of 55 mV dec −1 . This work reveals that the strong electronic interaction between Ir- and La-based materials can efficiently improve activity and reduce energy consumption, as well as enlarging the family of acidic OER electrocatalysts. The interaction between Ir and La via O atoms as a bridge in a-IrO x /LaCO 3 OH boosts the acidic OER activity of a-IrO x .