Loading…
Understanding a ligand's effects on intra-cluster and inter-cluster assembly
Ligands play an essential role in cluster assembly; however, understanding this behavior at the atomic level is far off. In this work, Cd 12 Ag 32 (S-PhOMe) 36 (PPh) 4 @Cd 6 Ag 2 (S-PhOMe) 6 Cl 6 (PPh 3 ) 8 @Ag 6 (S-PhOMe) 6 Cl 2 (Abbrev. Cd 12 Ag 32 -1 ) and Cd 12 Ag 32 (S- c -C 6 H 11 ) 36 (Abbrev...
Saved in:
| Published in: | Nanoscale 2022-06, Vol.14 (24), p.8842-8848 |
|---|---|
| Main Authors: | , , , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c267t-a5bc1772411dcf263bbbd65240d3d7f8592e55b1b671ef1687265798d182d37e3 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c267t-a5bc1772411dcf263bbbd65240d3d7f8592e55b1b671ef1687265798d182d37e3 |
| container_end_page | 8848 |
| container_issue | 24 |
| container_start_page | 8842 |
| container_title | Nanoscale |
| container_volume | 14 |
| creator | Tang, Li Yin, Zhengmao Wang, Ru Wang, Bin Jiang, Kefan Ding, Mei Wang, Shuxin |
| description | Ligands play an essential role in cluster assembly; however, understanding this behavior at the atomic level is far off. In this work, Cd
12
Ag
32
(S-PhOMe)
36
(PPh)
4
@Cd
6
Ag
2
(S-PhOMe)
6
Cl
6
(PPh
3
)
8
@Ag
6
(S-PhOMe)
6
Cl
2
(Abbrev.
Cd
12
Ag
32
-1
) and Cd
12
Ag
32
(S-
c
-C
6
H
11
)
36
(Abbrev.
Cd
12
Ag
32
-2
) were synthesized and structurally determined by single-crystal X-ray diffraction. An important finding is the selective adsorption of phosphine ligands that is caused by the different types of thiol ligands. In addition,
Cd
12
Ag
32
-1
follows a unique stacking pattern in a superlattice with multiple inter-cluster channels. Overall, this study is helpful for an in-depth understanding of the effect of mixed ligands on nanocluster formation and the correlation between structure and properties in the nanocluster range.
Ligands play an essential role in cluster assembly; however, understanding this behavior at the atomic level is far off. |
| doi_str_mv | 10.1039/d2nr01765b |
| format | article |
| fullrecord | <record><control><sourceid>proquest_rsc_p</sourceid><recordid>TN_cdi_rsc_primary_d2nr01765b</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2679688367</sourcerecordid><originalsourceid>FETCH-LOGICAL-c267t-a5bc1772411dcf263bbbd65240d3d7f8592e55b1b671ef1687265798d182d37e3</originalsourceid><addsrcrecordid>eNpd0c9LwzAUB_AgipvTi3el4EERqvnRJO1xzp8wFMSdS5O8jo42nUl72H9v5uYGnvJ478NL-Aahc4LvCGbZvaHWYSIFVwdoSHGCY8YkPdzVIhmgE-8XGIuMCXaMBoyLjDOGh2g6swac7wprKjuPiqiu5qG-9hGUJejOR62NKtu5ItZ17ztwURivO-D2He-hUfXqFB2VRe3hbHuO0Oz56WvyGk8_Xt4m42msqZBdXHCliZQ0IcTokgqmlDKC0wQbZmSZ8owC54ooIQmURKSSCi6z1JCUGiaBjdDNZu_Std89-C5vKq-hrgsLbe_zcAvP0kQSHujVP7poe2fD69YqE2nKhAzqdqO0a713UOZLVzWFW-UE5-uM80f6_vmb8UPAl9uVvWrA7OhfqAFcbIDzejfdfxL7Af-Tf2s</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2679688367</pqid></control><display><type>article</type><title>Understanding a ligand's effects on intra-cluster and inter-cluster assembly</title><source>Royal Society of Chemistry Journals</source><creator>Tang, Li ; Yin, Zhengmao ; Wang, Ru ; Wang, Bin ; Jiang, Kefan ; Ding, Mei ; Wang, Shuxin</creator><creatorcontrib>Tang, Li ; Yin, Zhengmao ; Wang, Ru ; Wang, Bin ; Jiang, Kefan ; Ding, Mei ; Wang, Shuxin</creatorcontrib><description>Ligands play an essential role in cluster assembly; however, understanding this behavior at the atomic level is far off. In this work, Cd
12
Ag
32
(S-PhOMe)
36
(PPh)
4
@Cd
6
Ag
2
(S-PhOMe)
6
Cl
6
(PPh
3
)
8
@Ag
6
(S-PhOMe)
6
Cl
2
(Abbrev.
Cd
12
Ag
32
-1
) and Cd
12
Ag
32
(S-
c
-C
6
H
11
)
36
(Abbrev.
Cd
12
Ag
32
-2
) were synthesized and structurally determined by single-crystal X-ray diffraction. An important finding is the selective adsorption of phosphine ligands that is caused by the different types of thiol ligands. In addition,
Cd
12
Ag
32
-1
follows a unique stacking pattern in a superlattice with multiple inter-cluster channels. Overall, this study is helpful for an in-depth understanding of the effect of mixed ligands on nanocluster formation and the correlation between structure and properties in the nanocluster range.
Ligands play an essential role in cluster assembly; however, understanding this behavior at the atomic level is far off.</description><identifier>ISSN: 2040-3364</identifier><identifier>EISSN: 2040-3372</identifier><identifier>DOI: 10.1039/d2nr01765b</identifier><identifier>PMID: 35695330</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Assembly ; Clusters ; Crystal structure ; Ligands ; Nanoclusters ; Phosphines ; Selective adsorption ; Single crystals ; Superlattices</subject><ispartof>Nanoscale, 2022-06, Vol.14 (24), p.8842-8848</ispartof><rights>Copyright Royal Society of Chemistry 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c267t-a5bc1772411dcf263bbbd65240d3d7f8592e55b1b671ef1687265798d182d37e3</citedby><cites>FETCH-LOGICAL-c267t-a5bc1772411dcf263bbbd65240d3d7f8592e55b1b671ef1687265798d182d37e3</cites><orcidid>0000-0003-0403-3953</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27900,27901</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/35695330$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Tang, Li</creatorcontrib><creatorcontrib>Yin, Zhengmao</creatorcontrib><creatorcontrib>Wang, Ru</creatorcontrib><creatorcontrib>Wang, Bin</creatorcontrib><creatorcontrib>Jiang, Kefan</creatorcontrib><creatorcontrib>Ding, Mei</creatorcontrib><creatorcontrib>Wang, Shuxin</creatorcontrib><title>Understanding a ligand's effects on intra-cluster and inter-cluster assembly</title><title>Nanoscale</title><addtitle>Nanoscale</addtitle><description>Ligands play an essential role in cluster assembly; however, understanding this behavior at the atomic level is far off. In this work, Cd
12
Ag
32
(S-PhOMe)
36
(PPh)
4
@Cd
6
Ag
2
(S-PhOMe)
6
Cl
6
(PPh
3
)
8
@Ag
6
(S-PhOMe)
6
Cl
2
(Abbrev.
Cd
12
Ag
32
-1
) and Cd
12
Ag
32
(S-
c
-C
6
H
11
)
36
(Abbrev.
Cd
12
Ag
32
-2
) were synthesized and structurally determined by single-crystal X-ray diffraction. An important finding is the selective adsorption of phosphine ligands that is caused by the different types of thiol ligands. In addition,
Cd
12
Ag
32
-1
follows a unique stacking pattern in a superlattice with multiple inter-cluster channels. Overall, this study is helpful for an in-depth understanding of the effect of mixed ligands on nanocluster formation and the correlation between structure and properties in the nanocluster range.
Ligands play an essential role in cluster assembly; however, understanding this behavior at the atomic level is far off.</description><subject>Assembly</subject><subject>Clusters</subject><subject>Crystal structure</subject><subject>Ligands</subject><subject>Nanoclusters</subject><subject>Phosphines</subject><subject>Selective adsorption</subject><subject>Single crystals</subject><subject>Superlattices</subject><issn>2040-3364</issn><issn>2040-3372</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpd0c9LwzAUB_AgipvTi3el4EERqvnRJO1xzp8wFMSdS5O8jo42nUl72H9v5uYGnvJ478NL-Aahc4LvCGbZvaHWYSIFVwdoSHGCY8YkPdzVIhmgE-8XGIuMCXaMBoyLjDOGh2g6swac7wprKjuPiqiu5qG-9hGUJejOR62NKtu5ItZ17ztwURivO-D2He-hUfXqFB2VRe3hbHuO0Oz56WvyGk8_Xt4m42msqZBdXHCliZQ0IcTokgqmlDKC0wQbZmSZ8owC54ooIQmURKSSCi6z1JCUGiaBjdDNZu_Std89-C5vKq-hrgsLbe_zcAvP0kQSHujVP7poe2fD69YqE2nKhAzqdqO0a713UOZLVzWFW-UE5-uM80f6_vmb8UPAl9uVvWrA7OhfqAFcbIDzejfdfxL7Af-Tf2s</recordid><startdate>20220623</startdate><enddate>20220623</enddate><creator>Tang, Li</creator><creator>Yin, Zhengmao</creator><creator>Wang, Ru</creator><creator>Wang, Bin</creator><creator>Jiang, Kefan</creator><creator>Ding, Mei</creator><creator>Wang, Shuxin</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-0403-3953</orcidid></search><sort><creationdate>20220623</creationdate><title>Understanding a ligand's effects on intra-cluster and inter-cluster assembly</title><author>Tang, Li ; Yin, Zhengmao ; Wang, Ru ; Wang, Bin ; Jiang, Kefan ; Ding, Mei ; Wang, Shuxin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c267t-a5bc1772411dcf263bbbd65240d3d7f8592e55b1b671ef1687265798d182d37e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Assembly</topic><topic>Clusters</topic><topic>Crystal structure</topic><topic>Ligands</topic><topic>Nanoclusters</topic><topic>Phosphines</topic><topic>Selective adsorption</topic><topic>Single crystals</topic><topic>Superlattices</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tang, Li</creatorcontrib><creatorcontrib>Yin, Zhengmao</creatorcontrib><creatorcontrib>Wang, Ru</creatorcontrib><creatorcontrib>Wang, Bin</creatorcontrib><creatorcontrib>Jiang, Kefan</creatorcontrib><creatorcontrib>Ding, Mei</creatorcontrib><creatorcontrib>Wang, Shuxin</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Nanoscale</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tang, Li</au><au>Yin, Zhengmao</au><au>Wang, Ru</au><au>Wang, Bin</au><au>Jiang, Kefan</au><au>Ding, Mei</au><au>Wang, Shuxin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Understanding a ligand's effects on intra-cluster and inter-cluster assembly</atitle><jtitle>Nanoscale</jtitle><addtitle>Nanoscale</addtitle><date>2022-06-23</date><risdate>2022</risdate><volume>14</volume><issue>24</issue><spage>8842</spage><epage>8848</epage><pages>8842-8848</pages><issn>2040-3364</issn><eissn>2040-3372</eissn><abstract>Ligands play an essential role in cluster assembly; however, understanding this behavior at the atomic level is far off. In this work, Cd
12
Ag
32
(S-PhOMe)
36
(PPh)
4
@Cd
6
Ag
2
(S-PhOMe)
6
Cl
6
(PPh
3
)
8
@Ag
6
(S-PhOMe)
6
Cl
2
(Abbrev.
Cd
12
Ag
32
-1
) and Cd
12
Ag
32
(S-
c
-C
6
H
11
)
36
(Abbrev.
Cd
12
Ag
32
-2
) were synthesized and structurally determined by single-crystal X-ray diffraction. An important finding is the selective adsorption of phosphine ligands that is caused by the different types of thiol ligands. In addition,
Cd
12
Ag
32
-1
follows a unique stacking pattern in a superlattice with multiple inter-cluster channels. Overall, this study is helpful for an in-depth understanding of the effect of mixed ligands on nanocluster formation and the correlation between structure and properties in the nanocluster range.
Ligands play an essential role in cluster assembly; however, understanding this behavior at the atomic level is far off.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>35695330</pmid><doi>10.1039/d2nr01765b</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0003-0403-3953</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2040-3364 |
| ispartof | Nanoscale, 2022-06, Vol.14 (24), p.8842-8848 |
| issn | 2040-3364 2040-3372 |
| language | eng |
| recordid | cdi_rsc_primary_d2nr01765b |
| source | Royal Society of Chemistry Journals |
| subjects | Assembly Clusters Crystal structure Ligands Nanoclusters Phosphines Selective adsorption Single crystals Superlattices |
| title | Understanding a ligand's effects on intra-cluster and inter-cluster assembly |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-24T21%3A20%3A18IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_rsc_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Understanding%20a%20ligand's%20effects%20on%20intra-cluster%20and%20inter-cluster%20assembly&rft.jtitle=Nanoscale&rft.au=Tang,%20Li&rft.date=2022-06-23&rft.volume=14&rft.issue=24&rft.spage=8842&rft.epage=8848&rft.pages=8842-8848&rft.issn=2040-3364&rft.eissn=2040-3372&rft_id=info:doi/10.1039/d2nr01765b&rft_dat=%3Cproquest_rsc_p%3E2679688367%3C/proquest_rsc_p%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c267t-a5bc1772411dcf263bbbd65240d3d7f8592e55b1b671ef1687265798d182d37e3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2679688367&rft_id=info:pmid/35695330&rfr_iscdi=true |