Highly twisted bipolar molecules for efficient near-ultraviolet organic light-emitting diodes a hybridized local and charge-transfer mechanism

• Published in: Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2023-02, Vol.11 (5), p.1733-1741
• Main Authors: Zhong, Ziting, Liu, Zhangshan, Geng, Sinuo, Li, Huihui, Feng, Xin Jiang, Zhao, Zujin, Lu, Hua
• Format: Article
• ISSN: 2050-7526; 2050-7534
• DOI: 10.1039/d2tc04421h

Near ultraviolet (NUV) electroluminescence (EL) is very important but seldom reported for being short of short-wavelength emitters. Herein, we report two highly twisted terphenyl-based donor-acceptor molecules exhibiting excellent thermal and morphological stability and nearly quantitative NUV luminescence. Via a hybridized local and charge-transfer (HLCT) process, excellent NUV EL is achieved with a maximum external quantum efficiency of 6.97% and CIE x , y of (0.16, 0.06) in a nondoped OLED. The device shows excellent colour purity with a small full width at half maximum of 48 nm. Our research demonstrates that highly twisted structures can efficiently tune the luminescence wavelength of bipolar molecules to the NUV region and achieve high-performance NUV EL. Using a twisting linker strategy, stable NUV luminogens are prepared with nearly quantitative luminescence. Nondoped OLEDs are fabricated using the dyes as emitters and NUV electroluminescence is achieved with a maximum EQE of 6.97% and a small FWHM of 48 nm.