A tetranuclear magnesium hydride cluster with a four-coordinate hydride in near square-planar geometry

A tetranuclear magnesium hydride complex based on the β-oxo-δ-diiminate (BODDI) ligand was isolated. In the solid state, the complex features three bridging μ 2 -hydrides and one unprecedented four-coordinate hydride in a nearly square-planar coordination environment. In the solid state, two differe...

Full description

Saved in:
Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2023-06, Vol.59 (49), p.7627-763
Main Authors: Seifert, Fabian, Görls, Helmar, Kupfer, Stephan, Kretschmer, Robert
Format: Article
Language:English
Subjects:
Coordination polymers
Hydrides
Magnesium
Solid state
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c337t-deda1c6b4c5dc2bac70457add4df7f6851e7614d8a83cea79eaed664d362d6f3
cites cdi_FETCH-LOGICAL-c337t-deda1c6b4c5dc2bac70457add4df7f6851e7614d8a83cea79eaed664d362d6f3
container_end_page 763
container_issue 49
container_start_page 7627
container_title Chemical communications (Cambridge, England)
container_volume 59
creator Seifert, Fabian
Görls, Helmar
Kupfer, Stephan
Kretschmer, Robert
description A tetranuclear magnesium hydride complex based on the β-oxo-δ-diiminate (BODDI) ligand was isolated. In the solid state, the complex features three bridging μ 2 -hydrides and one unprecedented four-coordinate hydride in a nearly square-planar coordination environment. In the solid state, two different coordination polymers are observed depending on whether the axial or equatorial oxygen lone pairs of 1,4-dioxane are engaged in bonding to magnesium. A dimeric magnesium hydride cluster has been synthesized. In the solid state it features a hydride ion that is coordinated to four magnesium ions at the same time in an unusual nearly square-planar fashion.
doi_str_mv 10.1039/d3cc01608k
format article
fullrecord <record><control><sourceid>proquest_rsc_p</sourceid><recordid>TN_cdi_rsc_primary_d3cc01608k</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2825828001</sourcerecordid><originalsourceid>FETCH-LOGICAL-c337t-deda1c6b4c5dc2bac70457add4df7f6851e7614d8a83cea79eaed664d362d6f3</originalsourceid><addsrcrecordid>eNpdkctLAzEQxoMotlYv3pUFLyKsbjbPHsv6xIKXHrwtaTLbbt1HTTZI_3uztlYwl8kwv_mY-Qahc5zc4oSM7wzROsE8kR8HaIgJpzGj8v2w_7NxLAhlA3Ti3CoJDzN5jAZEpIyFliEqJlEHnVWN1xUoG9Vq0YArfR0tN8aWBiJdedeBjb7KbhmpqGi9jXXbWlM2qoM9VjZR0wu4T68sxOtKNSFbQFsH-c0pOipU5eBsF0do9vgwy57j6dvTSzaZxpoQ0cUGjMKaz6lmRqdzpUVCmVDGUFOIgkuGQXBMjVSSaFBiDAoM59QQnhpekBG63squbfvpwXV5XToNVRgGWu_yVKaY0FRKEtCrf-gqbNaE4XqKyVQGswJ1s6W0bZ2zUORrW9bKbnKc5L35-T3Jsh_zXwN8uZP08xrMHv11OwAXW8A6va_-XY98A8lYiv4</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2825828001</pqid></control><display><type>article</type><title>A tetranuclear magnesium hydride cluster with a four-coordinate hydride in near square-planar geometry</title><source>Royal Society of Chemistry</source><creator>Seifert, Fabian ; Görls, Helmar ; Kupfer, Stephan ; Kretschmer, Robert</creator><creatorcontrib>Seifert, Fabian ; Görls, Helmar ; Kupfer, Stephan ; Kretschmer, Robert</creatorcontrib><description>A tetranuclear magnesium hydride complex based on the β-oxo-δ-diiminate (BODDI) ligand was isolated. In the solid state, the complex features three bridging μ 2 -hydrides and one unprecedented four-coordinate hydride in a nearly square-planar coordination environment. In the solid state, two different coordination polymers are observed depending on whether the axial or equatorial oxygen lone pairs of 1,4-dioxane are engaged in bonding to magnesium. A dimeric magnesium hydride cluster has been synthesized. In the solid state it features a hydride ion that is coordinated to four magnesium ions at the same time in an unusual nearly square-planar fashion.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/d3cc01608k</identifier><identifier>PMID: 37255016</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Coordination polymers ; Hydrides ; Magnesium ; Solid state</subject><ispartof>Chemical communications (Cambridge, England), 2023-06, Vol.59 (49), p.7627-763</ispartof><rights>Copyright Royal Society of Chemistry 2023</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c337t-deda1c6b4c5dc2bac70457add4df7f6851e7614d8a83cea79eaed664d362d6f3</citedby><cites>FETCH-LOGICAL-c337t-deda1c6b4c5dc2bac70457add4df7f6851e7614d8a83cea79eaed664d362d6f3</cites><orcidid>0000-0002-7731-3748 ; 0000-0002-6428-7528</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/37255016$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Seifert, Fabian</creatorcontrib><creatorcontrib>Görls, Helmar</creatorcontrib><creatorcontrib>Kupfer, Stephan</creatorcontrib><creatorcontrib>Kretschmer, Robert</creatorcontrib><title>A tetranuclear magnesium hydride cluster with a four-coordinate hydride in near square-planar geometry</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>A tetranuclear magnesium hydride complex based on the β-oxo-δ-diiminate (BODDI) ligand was isolated. In the solid state, the complex features three bridging μ 2 -hydrides and one unprecedented four-coordinate hydride in a nearly square-planar coordination environment. In the solid state, two different coordination polymers are observed depending on whether the axial or equatorial oxygen lone pairs of 1,4-dioxane are engaged in bonding to magnesium. A dimeric magnesium hydride cluster has been synthesized. In the solid state it features a hydride ion that is coordinated to four magnesium ions at the same time in an unusual nearly square-planar fashion.</description><subject>Coordination polymers</subject><subject>Hydrides</subject><subject>Magnesium</subject><subject>Solid state</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpdkctLAzEQxoMotlYv3pUFLyKsbjbPHsv6xIKXHrwtaTLbbt1HTTZI_3uztlYwl8kwv_mY-Qahc5zc4oSM7wzROsE8kR8HaIgJpzGj8v2w_7NxLAhlA3Ti3CoJDzN5jAZEpIyFliEqJlEHnVWN1xUoG9Vq0YArfR0tN8aWBiJdedeBjb7KbhmpqGi9jXXbWlM2qoM9VjZR0wu4T68sxOtKNSFbQFsH-c0pOipU5eBsF0do9vgwy57j6dvTSzaZxpoQ0cUGjMKaz6lmRqdzpUVCmVDGUFOIgkuGQXBMjVSSaFBiDAoM59QQnhpekBG63squbfvpwXV5XToNVRgGWu_yVKaY0FRKEtCrf-gqbNaE4XqKyVQGswJ1s6W0bZ2zUORrW9bKbnKc5L35-T3Jsh_zXwN8uZP08xrMHv11OwAXW8A6va_-XY98A8lYiv4</recordid><startdate>20230615</startdate><enddate>20230615</enddate><creator>Seifert, Fabian</creator><creator>Görls, Helmar</creator><creator>Kupfer, Stephan</creator><creator>Kretschmer, Robert</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-7731-3748</orcidid><orcidid>https://orcid.org/0000-0002-6428-7528</orcidid></search><sort><creationdate>20230615</creationdate><title>A tetranuclear magnesium hydride cluster with a four-coordinate hydride in near square-planar geometry</title><author>Seifert, Fabian ; Görls, Helmar ; Kupfer, Stephan ; Kretschmer, Robert</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-deda1c6b4c5dc2bac70457add4df7f6851e7614d8a83cea79eaed664d362d6f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Coordination polymers</topic><topic>Hydrides</topic><topic>Magnesium</topic><topic>Solid state</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Seifert, Fabian</creatorcontrib><creatorcontrib>Görls, Helmar</creatorcontrib><creatorcontrib>Kupfer, Stephan</creatorcontrib><creatorcontrib>Kretschmer, Robert</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Seifert, Fabian</au><au>Görls, Helmar</au><au>Kupfer, Stephan</au><au>Kretschmer, Robert</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A tetranuclear magnesium hydride cluster with a four-coordinate hydride in near square-planar geometry</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2023-06-15</date><risdate>2023</risdate><volume>59</volume><issue>49</issue><spage>7627</spage><epage>763</epage><pages>7627-763</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>A tetranuclear magnesium hydride complex based on the β-oxo-δ-diiminate (BODDI) ligand was isolated. In the solid state, the complex features three bridging μ 2 -hydrides and one unprecedented four-coordinate hydride in a nearly square-planar coordination environment. In the solid state, two different coordination polymers are observed depending on whether the axial or equatorial oxygen lone pairs of 1,4-dioxane are engaged in bonding to magnesium. A dimeric magnesium hydride cluster has been synthesized. In the solid state it features a hydride ion that is coordinated to four magnesium ions at the same time in an unusual nearly square-planar fashion.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>37255016</pmid><doi>10.1039/d3cc01608k</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-7731-3748</orcidid><orcidid>https://orcid.org/0000-0002-6428-7528</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 1359-7345
ispartof Chemical communications (Cambridge, England), 2023-06, Vol.59 (49), p.7627-763
issn 1359-7345
1364-548X
language eng
recordid cdi_rsc_primary_d3cc01608k
source Royal Society of Chemistry
subjects Coordination polymers
Hydrides
Magnesium
Solid state
title A tetranuclear magnesium hydride cluster with a four-coordinate hydride in near square-planar geometry
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-24T20%3A56%3A38IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_rsc_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20tetranuclear%20magnesium%20hydride%20cluster%20with%20a%20four-coordinate%20hydride%20in%20near%20square-planar%20geometry&rft.jtitle=Chemical%20communications%20(Cambridge,%20England)&rft.au=Seifert,%20Fabian&rft.date=2023-06-15&rft.volume=59&rft.issue=49&rft.spage=7627&rft.epage=763&rft.pages=7627-763&rft.issn=1359-7345&rft.eissn=1364-548X&rft_id=info:doi/10.1039/d3cc01608k&rft_dat=%3Cproquest_rsc_p%3E2825828001%3C/proquest_rsc_p%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c337t-deda1c6b4c5dc2bac70457add4df7f6851e7614d8a83cea79eaed664d362d6f3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2825828001&rft_id=info:pmid/37255016&rfr_iscdi=true