A bromo(boryloxy) silylene and its heavier analogues

A N-heterocylic boryloxy ligand equipped with bulky diazaboryl N -substituents is used to synthesize divalent and dicoordinate group 14 compounds which represent the first examples of acyclic halo(boryloxy) tetrylenes. The bromo(boryloxy) silylene reacts swiftly with benzophenone to a siloxindane. A...

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Published in:Chemical communications (Cambridge, England) England), 2024-02, Vol.6 (12), p.1583-1586
Main Authors: Guthardt, Robin, Jones, Cameron
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description A N-heterocylic boryloxy ligand equipped with bulky diazaboryl N -substituents is used to synthesize divalent and dicoordinate group 14 compounds which represent the first examples of acyclic halo(boryloxy) tetrylenes. The bromo(boryloxy) silylene reacts swiftly with benzophenone to a siloxindane. A selection of halo tetrylenes was synthesized utilizing a bulky boryloxy ligand {B}* O. In a reaction of {B}* OSiBr with benzophenone we observed the formation of a siloxindane which is reminiscence of the behaviour of smaller cyclic silylenes.
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title A bromo(boryloxy) silylene and its heavier analogues
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