The NO reduction by CO over NiO/CeO catalysts with a fixed Ni surface density: pretreatment effects on the catalyst structure and catalytic activity

• Published in: Catalysis science & technology 2024-01, Vol.14 (2), p.279-292
• Main Authors: Lee, Kyung-Min, Kim, Byeongseok, Lee, Juwon, Kwon, Gihan, Yoon, Kwangsuk, Song, Hocheol, Min, Kyung Hoon, Shim, Sang Eun, Hwang, Sungwon, Kim, Taejin
• Format: Article
• ISSN: 2044-4753; 2044-4761
• DOI: 10.1039/d3cy01103h

NiO x /CeO 2 catalysts have shown promising results in various catalytic reactions, including the NO reduction by CO. In this study, we investigated the effect of oxidation and reduction treatments on the NO reduction by CO over pretreated NiO x /CeO 2 catalysts. A series of oxidized and reduced supported NiO x catalysts were synthesized in two steps: (1) the pretreatment of CeO 2 supports at different temperatures (400, 500, and 700 °C) under oxidizing and reducing conditions and (2) the synthesis of NiO x /CeO 2 catalysts by an incipient wetness impregnation method (IWI) with a fixed surface density of 5.3 Ni per nm 2 under specific conditions (oxidation/reduction) applied during the CeO 2 treatment. The prepared catalysts were characterized via BET, ICP/OES, Raman, XPS, and XRD to understand their physicochemical properties. The results showed that as the pretreatment temperature increased, the physicochemical properties of NiO x /CeO 2 catalysts were changed: a decreased specific surface area (SSA), decreased oxygen vacancy/defect sites, and an increased crystallite size. The oxidized NiO x /CeO 2 catalyst at a lower pretreatment temperature displayed a better catalytic activity, indicating that the physicochemical properties of the catalysts were key factors in enhancing the catalytic activity. To understand the intermediate species and reaction mechanism during the NO reduction by CO, an in situ DRIFTS study was performed and a possible reaction mechanism was also discussed. NiO x /CeO 2 catalysts were synthesized under various pretreatment conditions. Different pretreatment conditions significantly influenced the activity of the NO reduction by CO reaction.