Highly stereoselective synthesis of -alkenes electrochemical Ni-catalyzed hydroarylation of alkynes with aryl iodides

An electrochemical nickel catalyzed hydroarylation reaction of various alkynes is herein described. In this reaction, alkynes were coupled with aryl iodides by electrochemical Ni catalysis to obtain highly selective trans -olefins. The outstanding features of this protocol include mild reaction cond...

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Bibliographic Details
Published in:Organic & biomolecular chemistry 2023-06, Vol.21 (25), p.5189-5193
Main Authors: Zhang, Haoxiang, Guo, Lin, Yang, Chao, Xia, Wujiong
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Summary:An electrochemical nickel catalyzed hydroarylation reaction of various alkynes is herein described. In this reaction, alkynes were coupled with aryl iodides by electrochemical Ni catalysis to obtain highly selective trans -olefins. The outstanding features of this protocol include mild reaction conditions, operational simplicity, and excellent functional group tolerance. An electrochemical nickel catalyzed hydroarylation reaction of alkynes with aryl iodides is herein described.
ISSN:1477-0520
1477-0539
DOI:10.1039/d3ob00705g