Alkylimidazolium-based ionic liquids with tailored anions and cations for CO capture

• Published in: RSC advances 2024-01, Vol.14 (6), p.3985-3995
• Main Authors: Osman, Abdelbagi, Ziyada, Abobakr K, Khan, Abdul Majeed, Rajab, Fahd
• Format: Article
• ISSN: 2046-2069
• DOI: 10.1039/d3ra08335g

A systematic investigation was conducted in the present study to determine how various cations and anions affected the solubility of CO 2 . To investigate the influence of different cations and anions on the solubility of CO 2 , twelve ILs were synthesized, characterized, and utilized. These ILs comprised five distinct anions (dioctylsulfosuccinate [DOSS], triflouromethanesulfonate [TFMS], dodecylsulfate [DDS], 3-sulfobezoate [SBA], and benzene sulfonate [BS]), and four distinct cations (1-butyl-3-propanenitrile imidazolium [C 2 CN Bim], 1-hexyl-3-propanenitrile imidazolium [C 2 CN Him], 1-octyl-3-propanenitrile imidazolium [C 2 CN Oim], and 1-decyl-3-propanenitrile imidazolium [C 2 CN Dim]). The synthesized ILs were characterized using NMR and elemental analysis. Their moisture and halide contents were determined. The gravimetric method (MSB) was employed to determine the solubility of CO 2 at various pressures (20, 15, 10, 5, and 1 bar). In addition, the effects of temperature on the solubility of CO 2 were investigated. The constant of Henry's law ( k H ) was also calculated, along with thermodynamic properties including standard enthalpy (H 0 ), entropy (S 0 ), and Gibbs free energy (G 0 ). The effect of different cations and anions in alkylimidazolium-based ionic liquids on CO 2 solubility was investigated systematically.