Improved benchtop P NMR reaction monitoring Multi-Resonance SHARPER

On-line reaction monitoring of hydrogenation reactions featuring oxygen-sensitive organometallic complexes is done via a 31 P benchtop NMR spectrometer using the Multi-Resonance Sensitive Homogeneous And Resolved PEaks in Real time (MR-SHARPER) sequence. Signal enhancement generated by MR-SHARPER en...

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Bibliographic Details
Published in:Analytical methods 2024-08, Vol.16 (31), p.5399-542
Main Authors: Tadiello, Laura, Halse, Meghan E, Beweries, Torsten
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Summary:On-line reaction monitoring of hydrogenation reactions featuring oxygen-sensitive organometallic complexes is done via a 31 P benchtop NMR spectrometer using the Multi-Resonance Sensitive Homogeneous And Resolved PEaks in Real time (MR-SHARPER) sequence. Signal enhancement generated by MR-SHARPER enables monitoring of reactivity on the order of minutes that could not be followed with traditional 31 P{ 1 H} NMR detection. On-line reaction monitoring of hydrogenation reactions of oxygen-sensitive organometallic complexes is done via a 31 P benchtop NMR spectrometer using the Multi-Resonance Sensitive Homogeneous And Resolved PEaks in Real time (MR-SHARPER) sequence.
ISSN:1759-9660
1759-9679
DOI:10.1039/d4ay00948g