A dynamic covalent approach to [PtL] cages

A dynamic covalent approach was exploited to generate a family of homometallic [Pt n L 2 n ] 2 n + cage (predominantly [Pt 2 L 4 ] 4+ systems) architectures. The family of platinum( ii ) architectures were characterized using 1 H nuclear magnetic resonance (NMR) and diffusion ordered spectroscopy (D...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2024-04, Vol.6 (32), p.432-435
Main Authors: van Hilst, Quinn V. C, Pearcy, Aston C, Preston, Dan, Wright, L. James, Hartinger, Christian G, Brooks, Heather J. L, Crowley, James D
Format: Article
Language:English
Online Access:Get full text
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Summary:A dynamic covalent approach was exploited to generate a family of homometallic [Pt n L 2 n ] 2 n + cage (predominantly [Pt 2 L 4 ] 4+ systems) architectures. The family of platinum( ii ) architectures were characterized using 1 H nuclear magnetic resonance (NMR) and diffusion ordered spectroscopy (DOSY), electrospray ionization mass spectrometry (ESI-MS) and the molecular structures of two cages were determined by X-ray crystallography. A dynamic covalent approach was exploited to generate a family of homometallic [Pt n L 2 n ] 2 n + cage (predominantly [Pt 2 L 4 ] 4+ systems) architectures.
ISSN:1359-7345
1364-548X
DOI:10.1039/d4cc00323c