Construction of binary metal-organic cage-based materials a "covalently linked plus cage encapsulated" strategy

A strategy for constructing binary metal-organic cage (MOC)-based materials was developed. The cationic MOCs were covalently linked by organic linkers to a cationic extended network, whereas the anionic MOCs acted as counterions and were encapsulated in the network. Compared with the corresponding u...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2024-09, Vol.6 (75), p.1362-1365
Main Authors: Lai, Pei, Wu, Jia-Xuan, Wu, Liang-Hua, Li, Lai-Yi, Cai, Song-Liang, Zheng, Sheng-Run
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Summary:A strategy for constructing binary metal-organic cage (MOC)-based materials was developed. The cationic MOCs were covalently linked by organic linkers to a cationic extended network, whereas the anionic MOCs acted as counterions and were encapsulated in the network. Compared with the corresponding unary materials, the binary MOC-based materials exhibited improved porosity and adsorption performance. A new type of binary metal-organic cage-based material was constructed by a "covalently linked plus cage encapsulated" strategy, and this material showed improved porosity and adsorption performance compared with those of related unary materials.
ISSN:1359-7345
1364-548X
DOI:10.1039/d4cc02536a