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Triple -substitution reactions of B(CF) and [(CF)PF] with P(SiMe)
para -Substitution reactions on C 6 F 5 rings of Lewis acids have been exploited to achieve triply substituted derivatives. The reaction of B(C 6 F 5 ) 3 with P(SiMe 3 ) 3 ultimately affords the Lewis acid B(C 6 F 4 P(SiMe 3 ) 2 ) 3 1 . This species binds Lewis bases affording the adducts LB(C 6 F 4...
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| Published in: | Dalton transactions : an international journal of inorganic chemistry 2024-03, Vol.53 (13), p.5775-5778 |
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| Main Authors: | , , , , , , |
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| container_end_page | 5778 |
| container_issue | 13 |
| container_start_page | 5775 |
| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 53 |
| creator | Thomson, Jordan Michailovich, Sofia Miao, Linkun Farrell, Jeffrey M Murray, Jillian A Lough, Alan Stephan, Douglas W |
| description | para
-Substitution reactions on C
6
F
5
rings of Lewis acids have been exploited to achieve triply substituted derivatives. The reaction of B(C
6
F
5
)
3
with P(SiMe
3
)
3
ultimately affords the Lewis acid B(C
6
F
4
P(SiMe
3
)
2
)
3
1
. This species binds Lewis bases affording the adducts LB(C
6
F
4
P(SiMe
3
)
2
)
3
(L = MeCN
2
, OPEt
3
3
, PMe
3
4
, PBu
3
5
) and reacts with LiMe to give the salt [Li][MeB(C
6
F
4
P(SiMe
3
)
2
)
3
]·3THF
6
. It also reacts with H
2
O to give (L)B(C
6
F
4
PH
2
)
3
(L = H
2
O
7
, MeCN
8
). In an analogous fashion, [(C
6
F
5
)
3
PF][B(C
6
F
5
)
4
] was converted to [FP(C
6
F
4
P(SiMe
3
)
2
)
3
] [B(C
6
F
5
)
4
]
9
and subsequently to [(MeO)P(C
6
F
4
PH
2
)
3
][B(C
6
F
5
)
4
]
10
.
The triple
para
-substitution products B(C
6
F
4
P(SiMe
3
)
2
)
3
or [FP(C
6
F
4
P(SiMe
3
)
2
)
3
][B(C
6
F
5
)
4
] were prepared, while subsequent reactions gave (H
2
O)B(C
6
F
4
PH
2
)
3
and [(MeO)P(C
6
F
4
PH
2
)
3
][B(C
6
F
5
)
4
]. |
| doi_str_mv | 10.1039/d4dt00251b |
| format | article |
| fullrecord | <record><control><sourceid>rsc</sourceid><recordid>TN_cdi_rsc_primary_d4dt00251b</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>d4dt00251b</sourcerecordid><originalsourceid>FETCH-rsc_primary_d4dt00251b3</originalsourceid><addsrcrecordid>eNpjYBAyNNAzNDC21E8xSSkxMDAyNUxiYuA0NDE317U0MjZhgbONzDgYuIqLs4BqjAxMjTgZHEOKMgtyUhV0i0uTiksyS0pLMvPzFIpSE5NBjGKF_DQFJw1nN02FxLwUhWgQK8AtVqE8syRDIUAjONM3VZOHgTUtMac4lRdKczPIurmGOHvoFhUnxxcUZeYmFlXGI9xlTEgeAA-qOKo</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Triple -substitution reactions of B(CF) and [(CF)PF] with P(SiMe)</title><source>Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list)</source><creator>Thomson, Jordan ; Michailovich, Sofia ; Miao, Linkun ; Farrell, Jeffrey M ; Murray, Jillian A ; Lough, Alan ; Stephan, Douglas W</creator><creatorcontrib>Thomson, Jordan ; Michailovich, Sofia ; Miao, Linkun ; Farrell, Jeffrey M ; Murray, Jillian A ; Lough, Alan ; Stephan, Douglas W</creatorcontrib><description>para
-Substitution reactions on C
6
F
5
rings of Lewis acids have been exploited to achieve triply substituted derivatives. The reaction of B(C
6
F
5
)
3
with P(SiMe
3
)
3
ultimately affords the Lewis acid B(C
6
F
4
P(SiMe
3
)
2
)
3
1
. This species binds Lewis bases affording the adducts LB(C
6
F
4
P(SiMe
3
)
2
)
3
(L = MeCN
2
, OPEt
3
3
, PMe
3
4
, PBu
3
5
) and reacts with LiMe to give the salt [Li][MeB(C
6
F
4
P(SiMe
3
)
2
)
3
]·3THF
6
. It also reacts with H
2
O to give (L)B(C
6
F
4
PH
2
)
3
(L = H
2
O
7
, MeCN
8
). In an analogous fashion, [(C
6
F
5
)
3
PF][B(C
6
F
5
)
4
] was converted to [FP(C
6
F
4
P(SiMe
3
)
2
)
3
] [B(C
6
F
5
)
4
]
9
and subsequently to [(MeO)P(C
6
F
4
PH
2
)
3
][B(C
6
F
5
)
4
]
10
.
The triple
para
-substitution products B(C
6
F
4
P(SiMe
3
)
2
)
3
or [FP(C
6
F
4
P(SiMe
3
)
2
)
3
][B(C
6
F
5
)
4
] were prepared, while subsequent reactions gave (H
2
O)B(C
6
F
4
PH
2
)
3
and [(MeO)P(C
6
F
4
PH
2
)
3
][B(C
6
F
5
)
4
].</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d4dt00251b</identifier><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2024-03, Vol.53 (13), p.5775-5778</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Thomson, Jordan</creatorcontrib><creatorcontrib>Michailovich, Sofia</creatorcontrib><creatorcontrib>Miao, Linkun</creatorcontrib><creatorcontrib>Farrell, Jeffrey M</creatorcontrib><creatorcontrib>Murray, Jillian A</creatorcontrib><creatorcontrib>Lough, Alan</creatorcontrib><creatorcontrib>Stephan, Douglas W</creatorcontrib><title>Triple -substitution reactions of B(CF) and [(CF)PF] with P(SiMe)</title><title>Dalton transactions : an international journal of inorganic chemistry</title><description>para
-Substitution reactions on C
6
F
5
rings of Lewis acids have been exploited to achieve triply substituted derivatives. The reaction of B(C
6
F
5
)
3
with P(SiMe
3
)
3
ultimately affords the Lewis acid B(C
6
F
4
P(SiMe
3
)
2
)
3
1
. This species binds Lewis bases affording the adducts LB(C
6
F
4
P(SiMe
3
)
2
)
3
(L = MeCN
2
, OPEt
3
3
, PMe
3
4
, PBu
3
5
) and reacts with LiMe to give the salt [Li][MeB(C
6
F
4
P(SiMe
3
)
2
)
3
]·3THF
6
. It also reacts with H
2
O to give (L)B(C
6
F
4
PH
2
)
3
(L = H
2
O
7
, MeCN
8
). In an analogous fashion, [(C
6
F
5
)
3
PF][B(C
6
F
5
)
4
] was converted to [FP(C
6
F
4
P(SiMe
3
)
2
)
3
] [B(C
6
F
5
)
4
]
9
and subsequently to [(MeO)P(C
6
F
4
PH
2
)
3
][B(C
6
F
5
)
4
]
10
.
The triple
para
-substitution products B(C
6
F
4
P(SiMe
3
)
2
)
3
or [FP(C
6
F
4
P(SiMe
3
)
2
)
3
][B(C
6
F
5
)
4
] were prepared, while subsequent reactions gave (H
2
O)B(C
6
F
4
PH
2
)
3
and [(MeO)P(C
6
F
4
PH
2
)
3
][B(C
6
F
5
)
4
].</description><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNpjYBAyNNAzNDC21E8xSSkxMDAyNUxiYuA0NDE317U0MjZhgbONzDgYuIqLs4BqjAxMjTgZHEOKMgtyUhV0i0uTiksyS0pLMvPzFIpSE5NBjGKF_DQFJw1nN02FxLwUhWgQK8AtVqE8syRDIUAjONM3VZOHgTUtMac4lRdKczPIurmGOHvoFhUnxxcUZeYmFlXGI9xlTEgeAA-qOKo</recordid><startdate>20240326</startdate><enddate>20240326</enddate><creator>Thomson, Jordan</creator><creator>Michailovich, Sofia</creator><creator>Miao, Linkun</creator><creator>Farrell, Jeffrey M</creator><creator>Murray, Jillian A</creator><creator>Lough, Alan</creator><creator>Stephan, Douglas W</creator><scope/></search><sort><creationdate>20240326</creationdate><title>Triple -substitution reactions of B(CF) and [(CF)PF] with P(SiMe)</title><author>Thomson, Jordan ; Michailovich, Sofia ; Miao, Linkun ; Farrell, Jeffrey M ; Murray, Jillian A ; Lough, Alan ; Stephan, Douglas W</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_d4dt00251b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><creationdate>2024</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Thomson, Jordan</creatorcontrib><creatorcontrib>Michailovich, Sofia</creatorcontrib><creatorcontrib>Miao, Linkun</creatorcontrib><creatorcontrib>Farrell, Jeffrey M</creatorcontrib><creatorcontrib>Murray, Jillian A</creatorcontrib><creatorcontrib>Lough, Alan</creatorcontrib><creatorcontrib>Stephan, Douglas W</creatorcontrib><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Thomson, Jordan</au><au>Michailovich, Sofia</au><au>Miao, Linkun</au><au>Farrell, Jeffrey M</au><au>Murray, Jillian A</au><au>Lough, Alan</au><au>Stephan, Douglas W</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Triple -substitution reactions of B(CF) and [(CF)PF] with P(SiMe)</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><date>2024-03-26</date><risdate>2024</risdate><volume>53</volume><issue>13</issue><spage>5775</spage><epage>5778</epage><pages>5775-5778</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>para
-Substitution reactions on C
6
F
5
rings of Lewis acids have been exploited to achieve triply substituted derivatives. The reaction of B(C
6
F
5
)
3
with P(SiMe
3
)
3
ultimately affords the Lewis acid B(C
6
F
4
P(SiMe
3
)
2
)
3
1
. This species binds Lewis bases affording the adducts LB(C
6
F
4
P(SiMe
3
)
2
)
3
(L = MeCN
2
, OPEt
3
3
, PMe
3
4
, PBu
3
5
) and reacts with LiMe to give the salt [Li][MeB(C
6
F
4
P(SiMe
3
)
2
)
3
]·3THF
6
. It also reacts with H
2
O to give (L)B(C
6
F
4
PH
2
)
3
(L = H
2
O
7
, MeCN
8
). In an analogous fashion, [(C
6
F
5
)
3
PF][B(C
6
F
5
)
4
] was converted to [FP(C
6
F
4
P(SiMe
3
)
2
)
3
] [B(C
6
F
5
)
4
]
9
and subsequently to [(MeO)P(C
6
F
4
PH
2
)
3
][B(C
6
F
5
)
4
]
10
.
The triple
para
-substitution products B(C
6
F
4
P(SiMe
3
)
2
)
3
or [FP(C
6
F
4
P(SiMe
3
)
2
)
3
][B(C
6
F
5
)
4
] were prepared, while subsequent reactions gave (H
2
O)B(C
6
F
4
PH
2
)
3
and [(MeO)P(C
6
F
4
PH
2
)
3
][B(C
6
F
5
)
4
].</abstract><doi>10.1039/d4dt00251b</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2024-03, Vol.53 (13), p.5775-5778 |
| issn | 1477-9226 1477-9234 |
| language | |
| recordid | cdi_rsc_primary_d4dt00251b |
| source | Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list) |
| title | Triple -substitution reactions of B(CF) and [(CF)PF] with P(SiMe) |
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