Galloborates as ultraviolet nonlinear optical crystals: advances and perspectives

• Published in: Dalton transactions : an international journal of inorganic chemistry 2024-07, Vol.53 (29), p.1234-1242
• Main Authors: Lu, Jing-Yi, Ou, Yangfeifei, Jin, Cong-Cong, Cheng, Jian-Wen
• Format: Article
• Language: English
• Subjects: Alkaline earth metals; Borates; Crystal structure; Gallium; Halides; Nonlinear optics; Potassium phosphates; Second harmonic generation
• ISSN: 1477-9226; 1477-9234; 1477-9234
• DOI: 10.1039/d4dt01206b

Metal borates are excellent source materials for exploring short-wavelength nonlinear optical (NLO) crystals. Galloborates show rich structural chemistry with various coordination configurations of Ga cation and B-O anionic units and are suitable candidates as ultraviolet NLO crystals. Up to now, the shortest cut-off edge of galloborates was reported to be down to 190 nm in KCs 2 Ga(B 5 O 10 )(OH), while the largest second harmonic generation (SHG) effect of galloborates was reported to be up to 4.6 times that of KH 2 PO 4 (KDP) in Na 5 Ga[B 7 O 12 (OH)] 2 ·2B(OH) 3 . Herein, we give a detailed summary of the recent progress in NLO inorganic galloborates, where these galloborates are grouped into two types in terms of their compositions: (1) alkali/alkaline earth metal galloborates and (2) alkali/alkaline earth metal galloborate halides. We discuss their structural features, band gaps, and SHG intensities. Finally, we give future perspectives in this field. Noncentrosymmetric galloborates show rich structural chemistry with various B-O anionic units and the [GaO 4 ] tetrahedron and are suitable candidates as ultraviolet nonlinear optical crystals.