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A nonlinear optical crystal with deep-ultraviolet transparency and appropriate birefringence achieved using π-conjugated confined [BOF(OH)]
Finding a deep-ultraviolet (deep-UV, λ < 200 nm) nonlinear optical (NLO) crystal is vital to a number of advanced optical technologies, yet it remains a great challenge. Herein, we report a deep-UV NLO crystal, K 2 B 3 O 3 F 4 (OH) (KBOFH), composed of π-conjugated confined groups. It exhibits a...
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| Published in: | New journal of chemistry 2024-09, Vol.48 (35), p.15281-15286 |
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| Main Authors: | , , , , , , , , , |
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| container_end_page | 15286 |
| container_issue | 35 |
| container_start_page | 15281 |
| container_title | New journal of chemistry |
| container_volume | 48 |
| creator | Ouyang, Tao Chen, Xu Chen, Shanshan Li, Yanqiang Shang, Xiaoying Bai, Zhiyong Jiang, Ningtao Yan, Zhishuo Luo, Junhua Zhao, Sangen |
| description | Finding a deep-ultraviolet (deep-UV,
λ
< 200 nm) nonlinear optical (NLO) crystal is vital to a number of advanced optical technologies, yet it remains a great challenge. Herein, we report a deep-UV NLO crystal, K
2
B
3
O
3
F
4
(OH) (KBOFH), composed of π-conjugated confined groups. It exhibits a relatively large birefringence of 0.054@550 nm and a wide transparency window with an absorption edge below 200 nm. Theoretical calculations reveal that the observed optical properties of KBOFH originate from the confined π-conjugated [B
3
O
3
F
4
(OH)] unit, in which the π-conjugated interactions are decoupled by the tetrahedral non-π-conjugated [BO
2
F
2
] unit. This work provides an opportunity to design deep-UV NLO crystals containing π-conjugated confined groups.
Based on a π-conjugated confinement strategy, we designed and synthesized a deep-UV NLO crystal, K
2
B
3
O
3
F
4
(OH), exhibiting a moderate birefringence (0.054@550 nm) and deep-UV transparency ( |
| doi_str_mv | 10.1039/d4nj02834a |
| format | article |
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λ
< 200 nm) nonlinear optical (NLO) crystal is vital to a number of advanced optical technologies, yet it remains a great challenge. Herein, we report a deep-UV NLO crystal, K
2
B
3
O
3
F
4
(OH) (KBOFH), composed of π-conjugated confined groups. It exhibits a relatively large birefringence of 0.054@550 nm and a wide transparency window with an absorption edge below 200 nm. Theoretical calculations reveal that the observed optical properties of KBOFH originate from the confined π-conjugated [B
3
O
3
F
4
(OH)] unit, in which the π-conjugated interactions are decoupled by the tetrahedral non-π-conjugated [BO
2
F
2
] unit. This work provides an opportunity to design deep-UV NLO crystals containing π-conjugated confined groups.
Based on a π-conjugated confinement strategy, we designed and synthesized a deep-UV NLO crystal, K
2
B
3
O
3
F
4
(OH), exhibiting a moderate birefringence (0.054@550 nm) and deep-UV transparency (<200 nm).</description><identifier>ISSN: 1144-0546</identifier><identifier>EISSN: 1369-9261</identifier><identifier>DOI: 10.1039/d4nj02834a</identifier><ispartof>New journal of chemistry, 2024-09, Vol.48 (35), p.15281-15286</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Ouyang, Tao</creatorcontrib><creatorcontrib>Chen, Xu</creatorcontrib><creatorcontrib>Chen, Shanshan</creatorcontrib><creatorcontrib>Li, Yanqiang</creatorcontrib><creatorcontrib>Shang, Xiaoying</creatorcontrib><creatorcontrib>Bai, Zhiyong</creatorcontrib><creatorcontrib>Jiang, Ningtao</creatorcontrib><creatorcontrib>Yan, Zhishuo</creatorcontrib><creatorcontrib>Luo, Junhua</creatorcontrib><creatorcontrib>Zhao, Sangen</creatorcontrib><title>A nonlinear optical crystal with deep-ultraviolet transparency and appropriate birefringence achieved using π-conjugated confined [BOF(OH)]</title><title>New journal of chemistry</title><description>Finding a deep-ultraviolet (deep-UV,
λ
< 200 nm) nonlinear optical (NLO) crystal is vital to a number of advanced optical technologies, yet it remains a great challenge. Herein, we report a deep-UV NLO crystal, K
2
B
3
O
3
F
4
(OH) (KBOFH), composed of π-conjugated confined groups. It exhibits a relatively large birefringence of 0.054@550 nm and a wide transparency window with an absorption edge below 200 nm. Theoretical calculations reveal that the observed optical properties of KBOFH originate from the confined π-conjugated [B
3
O
3
F
4
(OH)] unit, in which the π-conjugated interactions are decoupled by the tetrahedral non-π-conjugated [BO
2
F
2
] unit. This work provides an opportunity to design deep-UV NLO crystals containing π-conjugated confined groups.
Based on a π-conjugated confinement strategy, we designed and synthesized a deep-UV NLO crystal, K
2
B
3
O
3
F
4
(OH), exhibiting a moderate birefringence (0.054@550 nm) and deep-UV transparency (<200 nm).</description><issn>1144-0546</issn><issn>1369-9261</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFjz9LBDEUxIMoeP5p7IVXahFNbuPqlioe111jJ3I8k7d3WWISkuzJdn4Av5tfyRSCpdX8mBkYhrEzKa6kaLpro_wg5neNwj02k03b8W7eyv3KUikublR7yI5yHoSQ8raVM_Z1Dz54Zz1hghCL1ehApymXqh-2bMEQRT66knBng6MClXyOmMjrCdAbwBhTiMliIXizifpk_aamBKi3lnZkYMzVgu9ProMfxk1tGqjY110DLw-rxcVqefl6wg56dJlOf_WYnS-enh-XPGW9rgPvmKb138Xmv_wHLJ1YRg</recordid><startdate>20240909</startdate><enddate>20240909</enddate><creator>Ouyang, Tao</creator><creator>Chen, Xu</creator><creator>Chen, Shanshan</creator><creator>Li, Yanqiang</creator><creator>Shang, Xiaoying</creator><creator>Bai, Zhiyong</creator><creator>Jiang, Ningtao</creator><creator>Yan, Zhishuo</creator><creator>Luo, Junhua</creator><creator>Zhao, Sangen</creator><scope/></search><sort><creationdate>20240909</creationdate><title>A nonlinear optical crystal with deep-ultraviolet transparency and appropriate birefringence achieved using π-conjugated confined [BOF(OH)]</title><author>Ouyang, Tao ; Chen, Xu ; Chen, Shanshan ; Li, Yanqiang ; Shang, Xiaoying ; Bai, Zhiyong ; Jiang, Ningtao ; Yan, Zhishuo ; Luo, Junhua ; Zhao, Sangen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_d4nj02834a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><creationdate>2024</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ouyang, Tao</creatorcontrib><creatorcontrib>Chen, Xu</creatorcontrib><creatorcontrib>Chen, Shanshan</creatorcontrib><creatorcontrib>Li, Yanqiang</creatorcontrib><creatorcontrib>Shang, Xiaoying</creatorcontrib><creatorcontrib>Bai, Zhiyong</creatorcontrib><creatorcontrib>Jiang, Ningtao</creatorcontrib><creatorcontrib>Yan, Zhishuo</creatorcontrib><creatorcontrib>Luo, Junhua</creatorcontrib><creatorcontrib>Zhao, Sangen</creatorcontrib><jtitle>New journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ouyang, Tao</au><au>Chen, Xu</au><au>Chen, Shanshan</au><au>Li, Yanqiang</au><au>Shang, Xiaoying</au><au>Bai, Zhiyong</au><au>Jiang, Ningtao</au><au>Yan, Zhishuo</au><au>Luo, Junhua</au><au>Zhao, Sangen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A nonlinear optical crystal with deep-ultraviolet transparency and appropriate birefringence achieved using π-conjugated confined [BOF(OH)]</atitle><jtitle>New journal of chemistry</jtitle><date>2024-09-09</date><risdate>2024</risdate><volume>48</volume><issue>35</issue><spage>15281</spage><epage>15286</epage><pages>15281-15286</pages><issn>1144-0546</issn><eissn>1369-9261</eissn><abstract>Finding a deep-ultraviolet (deep-UV,
λ
< 200 nm) nonlinear optical (NLO) crystal is vital to a number of advanced optical technologies, yet it remains a great challenge. Herein, we report a deep-UV NLO crystal, K
2
B
3
O
3
F
4
(OH) (KBOFH), composed of π-conjugated confined groups. It exhibits a relatively large birefringence of 0.054@550 nm and a wide transparency window with an absorption edge below 200 nm. Theoretical calculations reveal that the observed optical properties of KBOFH originate from the confined π-conjugated [B
3
O
3
F
4
(OH)] unit, in which the π-conjugated interactions are decoupled by the tetrahedral non-π-conjugated [BO
2
F
2
] unit. This work provides an opportunity to design deep-UV NLO crystals containing π-conjugated confined groups.
Based on a π-conjugated confinement strategy, we designed and synthesized a deep-UV NLO crystal, K
2
B
3
O
3
F
4
(OH), exhibiting a moderate birefringence (0.054@550 nm) and deep-UV transparency (<200 nm).</abstract><doi>10.1039/d4nj02834a</doi><tpages>6</tpages></addata></record> |
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| identifier | ISSN: 1144-0546 |
| ispartof | New journal of chemistry, 2024-09, Vol.48 (35), p.15281-15286 |
| issn | 1144-0546 1369-9261 |
| language | |
| recordid | cdi_rsc_primary_d4nj02834a |
| source | Royal Society of Chemistry |
| title | A nonlinear optical crystal with deep-ultraviolet transparency and appropriate birefringence achieved using π-conjugated confined [BOF(OH)] |
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