The CFTMS adduct of anthraquinone as a monomer for making polymers with potential as separation membranes

The readily prepared CF 3 TMS adduct of anthraquinone is shown to be an efficient monomer for superacid-catalysed step-growth polymerisations, as exemplified by its reaction with diphenyl ether. The resulting polymer ( BTFMA-DPE ) is produced rapidly, with high molecular mass, and shows promise as a...

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Published in:Polymer chemistry 2024-10, Vol.15 (42), p.4312-4318
Main Authors: Wu, Kim Jiayi, Tobin, John M, Ji, Anli, Shi, Yang, Ye, Chunchun, Nichol, Gary S, Fuoco, Alessio, Longo, Mariagiulia, Jansen, Johannes C, McKeown, Neil B
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Summary:The readily prepared CF 3 TMS adduct of anthraquinone is shown to be an efficient monomer for superacid-catalysed step-growth polymerisations, as exemplified by its reaction with diphenyl ether. The resulting polymer ( BTFMA-DPE ) is produced rapidly, with high molecular mass, and shows promise as a gas separation membrane material. The CF 3 TMS adduct of anthraquinone reacts with diphenyl ether via a superacid-catalysed step-growth polymerisation to give a polymer ( BTFMA-DPE ) with promise for making gas separation membranes.
ISSN:1759-9954
1759-9962
DOI:10.1039/d4py01002g