Advancements in double decarboxylative coupling reactions of carboxylic acids

The double decarboxylative coupling reaction between two (similar or different) molecules of carboxylic acids is an emerging area that has gained considerable attention as a new avenue for forging carbon-carbon bonds. Since this synthetic strategy only utilizes carboxylic acids as easily accessible,...

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Bibliographic Details
Published in:RSC advances 2024-05, Vol.14 (21), p.14919-14933
Main Authors: Behmagham, Farnaz, Tawfiq, Maha Mohammed, Poor Heravi, Mohammad Reza, Alsultany, Nahed Mahmood Ahmed, Ballal, Suhas, Bahair, Hala, Adthab, A. Husein, Arshadi, Sattar, Vessally, Esmail
Format: Article
Language:English
Subjects:
Carbon dioxide
Carboxylic acids
Chemical reactions
Chemistry
Covalent bonds
Halides
Reagents
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Summary:The double decarboxylative coupling reaction between two (similar or different) molecules of carboxylic acids is an emerging area that has gained considerable attention as a new avenue for forging carbon-carbon bonds. Since this synthetic strategy only utilizes carboxylic acids as easily accessible, non-toxic and stable starting materials, and extrudes carbon dioxide (CO 2 ) as the only waste by-product, it can be considered as an environmentally benign alternative to traditional coupling reactions which mainly rely on the use of toxic organic halides or organometallic reagents. The aim of this review is to highlight the recent advances and developments in this exciting new field that may serve as inspiration for future research to mature it. The double decarboxylative coupling reaction between two (similar or different) molecules of carboxylic acids is an emerging area that has gained considerable attention as a new avenue for forging carbon-carbon bonds.
ISSN:2046-2069
2046-2069
DOI:10.1039/d4ra01747a