CTAB-induced synthesis of two-dimensional copper oxalate particles: using -ascorbic acid as the source of oxalate ligand

• Published in: RSC advances 2024-07, Vol.14 (32), p.23225-23231
• Main Authors: Shen, Bo, Chen, Zhengqiu, Mao, Huaming, Yin, Jungang, Ren, Yu, Dai, Wei, Zhao, Shuanglong, Yang, Hongwei
• Format: Article
• ISSN: 2046-2069
• DOI: 10.1039/d4ra04181j

Copper oxalate is typically synthesized through a precipitation reaction involving copper salts mixed with oxalic acid or oxalate solutions. However, in this study, we were successful in synthesizing well-formed square-like copper oxalate particles under liquid-phase conditions at ambient temperature and pressure using ascorbic acid as the source of the oxalic acid ligand. The addition of cationic surfactant cetyltrimethylammonium bromide (CTAB) caused the morphology of copper oxalate particles to undergo a transition from three-dimensional to two-dimensional. And the inhibition of the assembly of primary copper oxalate nanocrystals along the [001] direction became stronger with the increase of CTAB concentration. The impact of CTAB on the crystallization, growth, and self-assembly processes of primary copper oxalate nanocrystals was analysed using various testing methods. Based on these analyses, the possible mechanism of CTAB-induced synthesis of two-dimensional copper oxalate particles was finally proposed. We report a new green synthesis of copper oxalate, CTAB induced three-dimensional to two-dimensional sheet transformation.