N,N'-Dibromo-N,N' 1,2-ethanediylbis(benzenesulphonamide) (BNBBS): a Safe, Neutral and Efficient Reagent for the Oxidation of Primary and Secondary Alcohols to Corresponding Carbonyl Compounds under Mild Conditions : research article

Efficient oxidation of various types of structurally diverse alcohols to the corresponding carbonyl compounds can be carried out with N,N'-dibromo-N,N'-1,2-ethanediylbis(benzenesulphonamide) in good to high yield of products in CH2Cl2 at room temperature. Primary (aliphatic, benzylic and a...

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Bibliographic Details
Published in:South African journal of chemistry 2008-01, Vol.61 (1), p.9-12
Main Authors: Khazaei, Ardeshir, Rostami, Amin, Mahboubifar, Marjan
Format: Article
Language:English
Subjects:
Alcohols
Carbonyl compounds
N,N'-dibromo-N,N'-1,2-ethanediylbis(benzenesulphonamide)
Oxidation
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Summary:Efficient oxidation of various types of structurally diverse alcohols to the corresponding carbonyl compounds can be carried out with N,N'-dibromo-N,N'-1,2-ethanediylbis(benzenesulphonamide) in good to high yield of products in CH2Cl2 at room temperature. Primary (aliphatic, benzylic and allylic) alcohols are oxidized with no over-oxidation to carboxylic acids.
ISSN:0379-4350