Palladium nanoparticles from a surfactant-modified hydroxysalt exchanged with tetrachloropalladate

Abstract Palladium nanoparticles supported in the interlayer space of hydroxysalts were obtained from zinc hydroxychloride via a prior intercalation of the anionic surfactant sodium dodecyl sulfate (DS), followed by an exchange with potassium tetrachloropalladate and its final reduction to metallic...

Full description

Saved in:
Bibliographic Details
Published in:Dyna (Medellín, Colombia) Colombia), 2018-09, Vol.85 (206), p.142-147
Main Authors: Martínez, Maby Mool, Ocampo-Cardona, Rogelio, Aguirre-Cortés, Jhon Mauricio, Giraldo, Oscar, Ríos-Vásquez, Luz Amalia
Format: Article
Language:Portuguese
Subjects:
ENGINEERING, MULTIDISCIPLINARY
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page 147
container_issue 206
container_start_page 142
container_title Dyna (Medellín, Colombia)
container_volume 85
creator Martínez, Maby Mool
Ocampo-Cardona, Rogelio
Aguirre-Cortés, Jhon Mauricio
Giraldo, Oscar
Ríos-Vásquez, Luz Amalia
description Abstract Palladium nanoparticles supported in the interlayer space of hydroxysalts were obtained from zinc hydroxychloride via a prior intercalation of the anionic surfactant sodium dodecyl sulfate (DS), followed by an exchange with potassium tetrachloropalladate and its final reduction to metallic palladium by ethanol. The final materials and their intermediates were characterized by several instrumental techniques such as PXRD, N2 adsorption, SEM, and TEM. The comparative analyses revealed clearly visible changes on structure, specific surface area and morphology of the reduced material with respect to the starting precursors. The analyses demonstrated that, upon modification of the starting material with the surfactant, the resulting material had a significantly enhanced interlayer space and BET area, which were fairly maintained until the reduced palladium-containing hydroxysalt was obtained.
doi_str_mv 10.15446/dyna.v85n206.68132
format article
fullrecord <record><control><sourceid>scielo</sourceid><recordid>TN_cdi_scielo_journals_S0012_73532018000300142</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><scielo_id>S0012_73532018000300142</scielo_id><sourcerecordid>S0012_73532018000300142</sourcerecordid><originalsourceid>FETCH-scielo_journals_S0012_735320180003001423</originalsourceid><addsrcrecordid>eNqVjk1uwjAUhL2gEj_lBGx8gaTPdhKyr0Askco-ethOY-TYyHYKuT2JxAW6GukbzachZMcgZ2VRVF9qdJj_1aXjUOVVzQRfkBUA49lelGJJ1jHeAIqSQb0i1zNai8oMPXXo_B1DMtLqSNvge4o0DqFFmdClrPfKtEYr2o0q-OcY0Saqn7JD9zvRh0kdTToFlJ31YVLNYkz6k3y0aKPevnND8uPh8n3KojTa-ubmh-CmovmZTzbzSQ6sBgAxgYKLfw9ese5RRQ</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Palladium nanoparticles from a surfactant-modified hydroxysalt exchanged with tetrachloropalladate</title><source>Publicly Available Content (ProQuest)</source><creator>Martínez, Maby Mool ; Ocampo-Cardona, Rogelio ; Aguirre-Cortés, Jhon Mauricio ; Giraldo, Oscar ; Ríos-Vásquez, Luz Amalia</creator><creatorcontrib>Martínez, Maby Mool ; Ocampo-Cardona, Rogelio ; Aguirre-Cortés, Jhon Mauricio ; Giraldo, Oscar ; Ríos-Vásquez, Luz Amalia</creatorcontrib><description>Abstract Palladium nanoparticles supported in the interlayer space of hydroxysalts were obtained from zinc hydroxychloride via a prior intercalation of the anionic surfactant sodium dodecyl sulfate (DS), followed by an exchange with potassium tetrachloropalladate and its final reduction to metallic palladium by ethanol. The final materials and their intermediates were characterized by several instrumental techniques such as PXRD, N2 adsorption, SEM, and TEM. The comparative analyses revealed clearly visible changes on structure, specific surface area and morphology of the reduced material with respect to the starting precursors. The analyses demonstrated that, upon modification of the starting material with the surfactant, the resulting material had a significantly enhanced interlayer space and BET area, which were fairly maintained until the reduced palladium-containing hydroxysalt was obtained.</description><identifier>ISSN: 0012-7353</identifier><identifier>DOI: 10.15446/dyna.v85n206.68132</identifier><language>por</language><publisher>Universidad Nacional de Colombia</publisher><subject>ENGINEERING, MULTIDISCIPLINARY</subject><ispartof>Dyna (Medellín, Colombia), 2018-09, Vol.85 (206), p.142-147</ispartof><rights>This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,777,781,882,27905,27906</link.rule.ids></links><search><creatorcontrib>Martínez, Maby Mool</creatorcontrib><creatorcontrib>Ocampo-Cardona, Rogelio</creatorcontrib><creatorcontrib>Aguirre-Cortés, Jhon Mauricio</creatorcontrib><creatorcontrib>Giraldo, Oscar</creatorcontrib><creatorcontrib>Ríos-Vásquez, Luz Amalia</creatorcontrib><title>Palladium nanoparticles from a surfactant-modified hydroxysalt exchanged with tetrachloropalladate</title><title>Dyna (Medellín, Colombia)</title><addtitle>Dyna rev.fac.nac.minas</addtitle><description>Abstract Palladium nanoparticles supported in the interlayer space of hydroxysalts were obtained from zinc hydroxychloride via a prior intercalation of the anionic surfactant sodium dodecyl sulfate (DS), followed by an exchange with potassium tetrachloropalladate and its final reduction to metallic palladium by ethanol. The final materials and their intermediates were characterized by several instrumental techniques such as PXRD, N2 adsorption, SEM, and TEM. The comparative analyses revealed clearly visible changes on structure, specific surface area and morphology of the reduced material with respect to the starting precursors. The analyses demonstrated that, upon modification of the starting material with the surfactant, the resulting material had a significantly enhanced interlayer space and BET area, which were fairly maintained until the reduced palladium-containing hydroxysalt was obtained.</description><subject>ENGINEERING, MULTIDISCIPLINARY</subject><issn>0012-7353</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNqVjk1uwjAUhL2gEj_lBGx8gaTPdhKyr0Askco-ethOY-TYyHYKuT2JxAW6GukbzachZMcgZ2VRVF9qdJj_1aXjUOVVzQRfkBUA49lelGJJ1jHeAIqSQb0i1zNai8oMPXXo_B1DMtLqSNvge4o0DqFFmdClrPfKtEYr2o0q-OcY0Saqn7JD9zvRh0kdTToFlJ31YVLNYkz6k3y0aKPevnND8uPh8n3KojTa-ubmh-CmovmZTzbzSQ6sBgAxgYKLfw9ese5RRQ</recordid><startdate>20180901</startdate><enddate>20180901</enddate><creator>Martínez, Maby Mool</creator><creator>Ocampo-Cardona, Rogelio</creator><creator>Aguirre-Cortés, Jhon Mauricio</creator><creator>Giraldo, Oscar</creator><creator>Ríos-Vásquez, Luz Amalia</creator><general>Universidad Nacional de Colombia</general><scope>GPN</scope></search><sort><creationdate>20180901</creationdate><title>Palladium nanoparticles from a surfactant-modified hydroxysalt exchanged with tetrachloropalladate</title><author>Martínez, Maby Mool ; Ocampo-Cardona, Rogelio ; Aguirre-Cortés, Jhon Mauricio ; Giraldo, Oscar ; Ríos-Vásquez, Luz Amalia</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-scielo_journals_S0012_735320180003001423</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>por</language><creationdate>2018</creationdate><topic>ENGINEERING, MULTIDISCIPLINARY</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Martínez, Maby Mool</creatorcontrib><creatorcontrib>Ocampo-Cardona, Rogelio</creatorcontrib><creatorcontrib>Aguirre-Cortés, Jhon Mauricio</creatorcontrib><creatorcontrib>Giraldo, Oscar</creatorcontrib><creatorcontrib>Ríos-Vásquez, Luz Amalia</creatorcontrib><collection>SciELO</collection><jtitle>Dyna (Medellín, Colombia)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Martínez, Maby Mool</au><au>Ocampo-Cardona, Rogelio</au><au>Aguirre-Cortés, Jhon Mauricio</au><au>Giraldo, Oscar</au><au>Ríos-Vásquez, Luz Amalia</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Palladium nanoparticles from a surfactant-modified hydroxysalt exchanged with tetrachloropalladate</atitle><jtitle>Dyna (Medellín, Colombia)</jtitle><addtitle>Dyna rev.fac.nac.minas</addtitle><date>2018-09-01</date><risdate>2018</risdate><volume>85</volume><issue>206</issue><spage>142</spage><epage>147</epage><pages>142-147</pages><issn>0012-7353</issn><abstract>Abstract Palladium nanoparticles supported in the interlayer space of hydroxysalts were obtained from zinc hydroxychloride via a prior intercalation of the anionic surfactant sodium dodecyl sulfate (DS), followed by an exchange with potassium tetrachloropalladate and its final reduction to metallic palladium by ethanol. The final materials and their intermediates were characterized by several instrumental techniques such as PXRD, N2 adsorption, SEM, and TEM. The comparative analyses revealed clearly visible changes on structure, specific surface area and morphology of the reduced material with respect to the starting precursors. The analyses demonstrated that, upon modification of the starting material with the surfactant, the resulting material had a significantly enhanced interlayer space and BET area, which were fairly maintained until the reduced palladium-containing hydroxysalt was obtained.</abstract><pub>Universidad Nacional de Colombia</pub><doi>10.15446/dyna.v85n206.68132</doi><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 0012-7353
ispartof Dyna (Medellín, Colombia), 2018-09, Vol.85 (206), p.142-147
issn 0012-7353
language por
recordid cdi_scielo_journals_S0012_73532018000300142
source Publicly Available Content (ProQuest)
subjects ENGINEERING, MULTIDISCIPLINARY
title Palladium nanoparticles from a surfactant-modified hydroxysalt exchanged with tetrachloropalladate
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-20T07%3A47%3A46IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-scielo&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Palladium%20nanoparticles%20from%20a%20surfactant-modified%20hydroxysalt%20exchanged%20with%20tetrachloropalladate&rft.jtitle=Dyna%20(Medelli%CC%81n,%20Colombia)&rft.au=Mart%C3%ADnez,%20Maby%20Mool&rft.date=2018-09-01&rft.volume=85&rft.issue=206&rft.spage=142&rft.epage=147&rft.pages=142-147&rft.issn=0012-7353&rft_id=info:doi/10.15446/dyna.v85n206.68132&rft_dat=%3Cscielo%3ES0012_73532018000300142%3C/scielo%3E%3Cgrp_id%3Ecdi_FETCH-scielo_journals_S0012_735320180003001423%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rft_scielo_id=S0012_73532018000300142&rfr_iscdi=true