Lanthanide dithiocarbamate complexes: efficient catalysts for the cyanosilylation of aldehydes

A new class of lanthanide dithiocarbamate complexes was used to promote the cyanosilylation of aldehydes at high yields at room temperature. This represents the first application of lanthanide dithiocarbamate acting as Lewis acid.

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Bibliographic Details
Published in:Journal of the Brazilian Chemical Society 2006-10, Vol.17 (5), p.829-831
Main Authors: Vale, Juliana A., Faustino, Wagner M., Menezes, Paulo H., Sá, Gilberto F. de
Format: Article
Language:English
Subjects:
CHEMISTRY, MULTIDISCIPLINARY
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Description
Summary:A new class of lanthanide dithiocarbamate complexes was used to promote the cyanosilylation of aldehydes at high yields at room temperature. This represents the first application of lanthanide dithiocarbamate acting as Lewis acid.
ISSN:0103-5053
1678-4790
DOI:10.1590/S0103-50532006000500002