Glycerol Electrooxidation in Alkaline Medium Using Pd/C, Au/C and PdAu/C Electrocatalysts Prepared by Electron Beam Irradiation

Pd/C, Au/C and PdAu/C electrocatalysts with different atomic ratios prepared using electron beam irradiation were tested for glycerol electrooxidation in single alkaline direct glycerol fuel cell (ADGFC). X-ray diffractograms (XRD) of PdAu/C electrocatalysts showed the presence of Pd (fcc) and Au (f...

Full description

Saved in:
Bibliographic Details
Published in:Journal of the Brazilian Chemical Society 2014-05, Vol.25 (5), p.831-840
Main Authors: Geraldes, Adriana N., Silva, Dionisio F., Silva, Júlio C. M., Souza, Rodrigo F. B., Spinacé, Estevam V., Oliveira Neto, Almir, Linardi, Marcelo, Santos, Mauro C.
Format: Article
Language:English
Subjects:
CHEMISTRY, MULTIDISCIPLINARY
Citations: Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c330t-ed6106703e6d222a9f702bc8a7be9962dc08db4d89efab6fe3deb7c62ace65e3
cites
container_end_page 840
container_issue 5
container_start_page 831
container_title Journal of the Brazilian Chemical Society
container_volume 25
creator Geraldes, Adriana N.
Silva, Dionisio F.
Silva, Júlio C. M.
Souza, Rodrigo F. B.
Spinacé, Estevam V.
Oliveira Neto, Almir
Linardi, Marcelo
Santos, Mauro C.
description Pd/C, Au/C and PdAu/C electrocatalysts with different atomic ratios prepared using electron beam irradiation were tested for glycerol electrooxidation in single alkaline direct glycerol fuel cell (ADGFC). X-ray diffractograms (XRD) of PdAu/C electrocatalysts showed the presence of Pd (fcc) and Au (fcc) phases. Cyclic voltammetry (CV) and chronoamperometry showed that PdAu/C electrocatalyst with Pd:Au atomic ratio of 50:50 demonstrated superior activity for glycerol electrooxidation, at room temperature. In situ Fourier transform infrared spectroscopy by attenuated total reflectance (ATR-FTIR) experiments were performed for the electrocatalysts, identifying oxalate, glycerate ion, 1,3-dihydroxy-2-propanone, glyceraldehyde and glycolate as products of glycerol electrooxidation. Experiments with single ADGFC were carried out from 50 to 90 ºC, using Pd/C electrocatalyst; the best performance was obtained at 80 ºC.
doi_str_mv 10.5935/0103-5053.20140044
format article
fullrecord <record><control><sourceid>scielo_cross</sourceid><recordid>TN_cdi_scielo_journals_S0103_50532014000500004</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><scielo_id>S0103_50532014000500004</scielo_id><sourcerecordid>S0103_50532014000500004</sourcerecordid><originalsourceid>FETCH-LOGICAL-c330t-ed6106703e6d222a9f702bc8a7be9962dc08db4d89efab6fe3deb7c62ace65e3</originalsourceid><addsrcrecordid>eNo9kEtOwzAQQL0AiVK4ACsfgLQTO06aZYlKqVREJcracuwJcnGTyk4lsuLqpN_FaH56M9Ij5CmGkci5GEMMPBIg-IhBnAAkyQ0ZXId35D6EDQATgrMB-Zu7TqNvHJ051K1vml9rVGubmtqaTt2PcrZG-o7G7rf0K9j6m67MuHim0_24oKo2fXssz7xWrXJdaANdedwpj4aW3WVZ0xdUW7rwXhl7_PJAbivlAj6e85CsX2fr4i1afswXxXQZac6hjdCkMaQZcEwNY0zlVQas1BOVlZjnKTMaJqZMzCTHSpVphdxgmemUKY2pQD4ko9PZoC26Rm6ava_7f_LzIEYexJxkgegDkh5gJ0D7JgSPldx5u1W-kzHIg2Z5BeVFM_8HB4dw0w</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Glycerol Electrooxidation in Alkaline Medium Using Pd/C, Au/C and PdAu/C Electrocatalysts Prepared by Electron Beam Irradiation</title><source>SciELO</source><creator>Geraldes, Adriana N. ; Silva, Dionisio F. ; Silva, Júlio C. M. ; Souza, Rodrigo F. B. ; Spinacé, Estevam V. ; Oliveira Neto, Almir ; Linardi, Marcelo ; Santos, Mauro C.</creator><creatorcontrib>Geraldes, Adriana N. ; Silva, Dionisio F. ; Silva, Júlio C. M. ; Souza, Rodrigo F. B. ; Spinacé, Estevam V. ; Oliveira Neto, Almir ; Linardi, Marcelo ; Santos, Mauro C.</creatorcontrib><description>Pd/C, Au/C and PdAu/C electrocatalysts with different atomic ratios prepared using electron beam irradiation were tested for glycerol electrooxidation in single alkaline direct glycerol fuel cell (ADGFC). X-ray diffractograms (XRD) of PdAu/C electrocatalysts showed the presence of Pd (fcc) and Au (fcc) phases. Cyclic voltammetry (CV) and chronoamperometry showed that PdAu/C electrocatalyst with Pd:Au atomic ratio of 50:50 demonstrated superior activity for glycerol electrooxidation, at room temperature. In situ Fourier transform infrared spectroscopy by attenuated total reflectance (ATR-FTIR) experiments were performed for the electrocatalysts, identifying oxalate, glycerate ion, 1,3-dihydroxy-2-propanone, glyceraldehyde and glycolate as products of glycerol electrooxidation. Experiments with single ADGFC were carried out from 50 to 90 ºC, using Pd/C electrocatalyst; the best performance was obtained at 80 ºC.</description><identifier>ISSN: 0103-5053</identifier><identifier>ISSN: 1678-4790</identifier><identifier>DOI: 10.5935/0103-5053.20140044</identifier><language>eng</language><publisher>Sociedade Brasileira de Química</publisher><subject>CHEMISTRY, MULTIDISCIPLINARY</subject><ispartof>Journal of the Brazilian Chemical Society, 2014-05, Vol.25 (5), p.831-840</ispartof><rights>This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c330t-ed6106703e6d222a9f702bc8a7be9962dc08db4d89efab6fe3deb7c62ace65e3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,776,780,881,24129,27901,27902</link.rule.ids></links><search><creatorcontrib>Geraldes, Adriana N.</creatorcontrib><creatorcontrib>Silva, Dionisio F.</creatorcontrib><creatorcontrib>Silva, Júlio C. M.</creatorcontrib><creatorcontrib>Souza, Rodrigo F. B.</creatorcontrib><creatorcontrib>Spinacé, Estevam V.</creatorcontrib><creatorcontrib>Oliveira Neto, Almir</creatorcontrib><creatorcontrib>Linardi, Marcelo</creatorcontrib><creatorcontrib>Santos, Mauro C.</creatorcontrib><title>Glycerol Electrooxidation in Alkaline Medium Using Pd/C, Au/C and PdAu/C Electrocatalysts Prepared by Electron Beam Irradiation</title><title>Journal of the Brazilian Chemical Society</title><addtitle>J. Braz. Chem. Soc</addtitle><description>Pd/C, Au/C and PdAu/C electrocatalysts with different atomic ratios prepared using electron beam irradiation were tested for glycerol electrooxidation in single alkaline direct glycerol fuel cell (ADGFC). X-ray diffractograms (XRD) of PdAu/C electrocatalysts showed the presence of Pd (fcc) and Au (fcc) phases. Cyclic voltammetry (CV) and chronoamperometry showed that PdAu/C electrocatalyst with Pd:Au atomic ratio of 50:50 demonstrated superior activity for glycerol electrooxidation, at room temperature. In situ Fourier transform infrared spectroscopy by attenuated total reflectance (ATR-FTIR) experiments were performed for the electrocatalysts, identifying oxalate, glycerate ion, 1,3-dihydroxy-2-propanone, glyceraldehyde and glycolate as products of glycerol electrooxidation. Experiments with single ADGFC were carried out from 50 to 90 ºC, using Pd/C electrocatalyst; the best performance was obtained at 80 ºC.</description><subject>CHEMISTRY, MULTIDISCIPLINARY</subject><issn>0103-5053</issn><issn>1678-4790</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNo9kEtOwzAQQL0AiVK4ACsfgLQTO06aZYlKqVREJcracuwJcnGTyk4lsuLqpN_FaH56M9Ij5CmGkci5GEMMPBIg-IhBnAAkyQ0ZXId35D6EDQATgrMB-Zu7TqNvHJ051K1vml9rVGubmtqaTt2PcrZG-o7G7rf0K9j6m67MuHim0_24oKo2fXssz7xWrXJdaANdedwpj4aW3WVZ0xdUW7rwXhl7_PJAbivlAj6e85CsX2fr4i1afswXxXQZac6hjdCkMaQZcEwNY0zlVQas1BOVlZjnKTMaJqZMzCTHSpVphdxgmemUKY2pQD4ko9PZoC26Rm6ava_7f_LzIEYexJxkgegDkh5gJ0D7JgSPldx5u1W-kzHIg2Z5BeVFM_8HB4dw0w</recordid><startdate>20140501</startdate><enddate>20140501</enddate><creator>Geraldes, Adriana N.</creator><creator>Silva, Dionisio F.</creator><creator>Silva, Júlio C. M.</creator><creator>Souza, Rodrigo F. B.</creator><creator>Spinacé, Estevam V.</creator><creator>Oliveira Neto, Almir</creator><creator>Linardi, Marcelo</creator><creator>Santos, Mauro C.</creator><general>Sociedade Brasileira de Química</general><scope>AAYXX</scope><scope>CITATION</scope><scope>GPN</scope></search><sort><creationdate>20140501</creationdate><title>Glycerol Electrooxidation in Alkaline Medium Using Pd/C, Au/C and PdAu/C Electrocatalysts Prepared by Electron Beam Irradiation</title><author>Geraldes, Adriana N. ; Silva, Dionisio F. ; Silva, Júlio C. M. ; Souza, Rodrigo F. B. ; Spinacé, Estevam V. ; Oliveira Neto, Almir ; Linardi, Marcelo ; Santos, Mauro C.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c330t-ed6106703e6d222a9f702bc8a7be9962dc08db4d89efab6fe3deb7c62ace65e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>CHEMISTRY, MULTIDISCIPLINARY</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Geraldes, Adriana N.</creatorcontrib><creatorcontrib>Silva, Dionisio F.</creatorcontrib><creatorcontrib>Silva, Júlio C. M.</creatorcontrib><creatorcontrib>Souza, Rodrigo F. B.</creatorcontrib><creatorcontrib>Spinacé, Estevam V.</creatorcontrib><creatorcontrib>Oliveira Neto, Almir</creatorcontrib><creatorcontrib>Linardi, Marcelo</creatorcontrib><creatorcontrib>Santos, Mauro C.</creatorcontrib><collection>CrossRef</collection><collection>SciELO</collection><jtitle>Journal of the Brazilian Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Geraldes, Adriana N.</au><au>Silva, Dionisio F.</au><au>Silva, Júlio C. M.</au><au>Souza, Rodrigo F. B.</au><au>Spinacé, Estevam V.</au><au>Oliveira Neto, Almir</au><au>Linardi, Marcelo</au><au>Santos, Mauro C.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Glycerol Electrooxidation in Alkaline Medium Using Pd/C, Au/C and PdAu/C Electrocatalysts Prepared by Electron Beam Irradiation</atitle><jtitle>Journal of the Brazilian Chemical Society</jtitle><addtitle>J. Braz. Chem. Soc</addtitle><date>2014-05-01</date><risdate>2014</risdate><volume>25</volume><issue>5</issue><spage>831</spage><epage>840</epage><pages>831-840</pages><issn>0103-5053</issn><issn>1678-4790</issn><abstract>Pd/C, Au/C and PdAu/C electrocatalysts with different atomic ratios prepared using electron beam irradiation were tested for glycerol electrooxidation in single alkaline direct glycerol fuel cell (ADGFC). X-ray diffractograms (XRD) of PdAu/C electrocatalysts showed the presence of Pd (fcc) and Au (fcc) phases. Cyclic voltammetry (CV) and chronoamperometry showed that PdAu/C electrocatalyst with Pd:Au atomic ratio of 50:50 demonstrated superior activity for glycerol electrooxidation, at room temperature. In situ Fourier transform infrared spectroscopy by attenuated total reflectance (ATR-FTIR) experiments were performed for the electrocatalysts, identifying oxalate, glycerate ion, 1,3-dihydroxy-2-propanone, glyceraldehyde and glycolate as products of glycerol electrooxidation. Experiments with single ADGFC were carried out from 50 to 90 ºC, using Pd/C electrocatalyst; the best performance was obtained at 80 ºC.</abstract><pub>Sociedade Brasileira de Química</pub><doi>10.5935/0103-5053.20140044</doi><tpages>10</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 0103-5053
ispartof Journal of the Brazilian Chemical Society, 2014-05, Vol.25 (5), p.831-840
issn 0103-5053
1678-4790
language eng
recordid cdi_scielo_journals_S0103_50532014000500004
source SciELO
subjects CHEMISTRY, MULTIDISCIPLINARY
title Glycerol Electrooxidation in Alkaline Medium Using Pd/C, Au/C and PdAu/C Electrocatalysts Prepared by Electron Beam Irradiation
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-01T08%3A13%3A37IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-scielo_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Glycerol%20Electrooxidation%20in%20Alkaline%20Medium%20Using%20Pd/C,%20Au/C%20and%20PdAu/C%20Electrocatalysts%20Prepared%20by%20Electron%20Beam%20Irradiation&rft.jtitle=Journal%20of%20the%20Brazilian%20Chemical%20Society&rft.au=Geraldes,%20Adriana%20N.&rft.date=2014-05-01&rft.volume=25&rft.issue=5&rft.spage=831&rft.epage=840&rft.pages=831-840&rft.issn=0103-5053&rft_id=info:doi/10.5935/0103-5053.20140044&rft_dat=%3Cscielo_cross%3ES0103_50532014000500004%3C/scielo_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c330t-ed6106703e6d222a9f702bc8a7be9962dc08db4d89efab6fe3deb7c62ace65e3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rft_scielo_id=S0103_50532014000500004&rfr_iscdi=true