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Concentration of Clusters in Nucleation and the Classical Phase Integral
A classical phase integral treatment of the equilibrium concentration of clusters in homogeneous nucleation from the vapor is discussed. It is concluded that the motions of a stationary cluster, i.e., a cluster in a bulk liquid, are more nearly those of translational and torsional vibration than fre...
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| Published in: | The Journal of chemical physics 1968-02, Vol.48 (4), p.1849-1852 |
|---|---|
| Main Authors: | , |
| Format: | Article |
| Language: | English |
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| Online Access: | Get full text |
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| cited_by | cdi_FETCH-LOGICAL-c365t-c3e69bee8cbff9af98564544030104579cd31252feb71816673fcd8e52104f3f3 |
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| cites | cdi_FETCH-LOGICAL-c365t-c3e69bee8cbff9af98564544030104579cd31252feb71816673fcd8e52104f3f3 |
| container_end_page | 1852 |
| container_issue | 4 |
| container_start_page | 1849 |
| container_title | The Journal of chemical physics |
| container_volume | 48 |
| creator | Lothe, Jens Pound, G. M. |
| description | A classical phase integral treatment of the equilibrium concentration of clusters in
homogeneous
nucleation from the vapor is discussed. It is concluded that the motions
of a stationary cluster, i.e., a cluster in a bulk liquid, are more nearly those of
translational and torsional vibration than free translation and rotation in a large free
volume. In this case one returns to the original Lothe‐Pound equation. Accordingly, the
1017 factor of correction to classical homogeneous nucleation theory
in condensation
still remains. |
| doi_str_mv | 10.1063/1.1668921 |
| format | article |
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homogeneous
nucleation from the vapor is discussed. It is concluded that the motions
of a stationary cluster, i.e., a cluster in a bulk liquid, are more nearly those of
translational and torsional vibration than free translation and rotation in a large free
volume. In this case one returns to the original Lothe‐Pound equation. Accordingly, the
1017 factor of correction to classical homogeneous nucleation theory
in condensation
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homogeneous
nucleation from the vapor is discussed. It is concluded that the motions
of a stationary cluster, i.e., a cluster in a bulk liquid, are more nearly those of
translational and torsional vibration than free translation and rotation in a large free
volume. In this case one returns to the original Lothe‐Pound equation. Accordingly, the
1017 factor of correction to classical homogeneous nucleation theory
in condensation
still remains.</description><issn>0021-9606</issn><issn>1089-7690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1968</creationdate><recordtype>article</recordtype><recordid>eNp9kEFLxDAQhYMouK4e_Ae5KnSdaZq0OUpRd2FRD3ouaTpxK7Vdkqzgv7faRQ-Cl5nD9_HgPcbOERYISlzhApUqdIoHbIZQ6CRXGg7ZDCDFRCtQx-wkhFcAwDzNZmxZDr2lPnoT26Hng-NltwuRfOBtz-93tqOJmL7hcUMjNiG01nT8cWMC8VUf6cWb7pQdOdMFOtv_OXu-vXkql8n64W5VXq8TK5SM4yWla6LC1s5p43QhVSazDAQgZDLXthGYytRRnWMxdsmFs01BMh2xE07M2cWUa_0QgidXbX37ZvxHhVB9TVBhtZ9gdC8nN9g2ftf4kd8H_ytW28b9J_9N_gQKXWmt</recordid><startdate>19680215</startdate><enddate>19680215</enddate><creator>Lothe, Jens</creator><creator>Pound, G. M.</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19680215</creationdate><title>Concentration of Clusters in Nucleation and the Classical Phase Integral</title><author>Lothe, Jens ; Pound, G. M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c365t-c3e69bee8cbff9af98564544030104579cd31252feb71816673fcd8e52104f3f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1968</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lothe, Jens</creatorcontrib><creatorcontrib>Pound, G. M.</creatorcontrib><collection>CrossRef</collection><jtitle>The Journal of chemical physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lothe, Jens</au><au>Pound, G. M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Concentration of Clusters in Nucleation and the Classical Phase Integral</atitle><jtitle>The Journal of chemical physics</jtitle><date>1968-02-15</date><risdate>1968</risdate><volume>48</volume><issue>4</issue><spage>1849</spage><epage>1852</epage><pages>1849-1852</pages><issn>0021-9606</issn><eissn>1089-7690</eissn><coden>JCPSA6</coden><abstract>A classical phase integral treatment of the equilibrium concentration of clusters in
homogeneous
nucleation from the vapor is discussed. It is concluded that the motions
of a stationary cluster, i.e., a cluster in a bulk liquid, are more nearly those of
translational and torsional vibration than free translation and rotation in a large free
volume. In this case one returns to the original Lothe‐Pound equation. Accordingly, the
1017 factor of correction to classical homogeneous nucleation theory
in condensation
still remains.</abstract><doi>10.1063/1.1668921</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0021-9606 |
| ispartof | The Journal of chemical physics, 1968-02, Vol.48 (4), p.1849-1852 |
| issn | 0021-9606 1089-7690 |
| language | eng |
| recordid | cdi_scitation_primary_10_1063_1_1668921 |
| source | AIP Journals (American Institute of Physics) |
| title | Concentration of Clusters in Nucleation and the Classical Phase Integral |
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