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Imaging and density mapping of tetrahydrofuran clathrate hydratesby phase-contrast x-ray computed tomography

In situ observations of tetrahydrofuran (THF) hydrates in THF solution using a phase-contrast x-ray imaging system at 273 K are reported. Density analysis measurements using phase-contrast x-ray imaging suggest that the inhomogeneous growth of THF hydrate crystals occurs due to differences in the ca...

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Published in:Applied physics letters 2007-02, Vol.90 (8), p.081920-081920-3
Main Authors: Takeya, Satoshi, Honda, Kazumasa, Kawamura, Taro, Yamamoto, Yoshitaka, Yoneyama, Akio, Hirai, Yasuharu, Hyodo, Kazuyuki, Takeda, Tohoru
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container_issue 8
container_start_page 081920
container_title Applied physics letters
container_volume 90
creator Takeya, Satoshi
Honda, Kazumasa
Kawamura, Taro
Yamamoto, Yoshitaka
Yoneyama, Akio
Hirai, Yasuharu
Hyodo, Kazuyuki
Takeda, Tohoru
description In situ observations of tetrahydrofuran (THF) hydrates in THF solution using a phase-contrast x-ray imaging system at 273 K are reported. Density analysis measurements using phase-contrast x-ray imaging suggest that the inhomogeneous growth of THF hydrate crystals occurs due to differences in the cage occupancy of guest molecules, caused by the diffusion of solute. Phase-contrast x-ray imaging developed in this study can also be applied to the time-resolved imaging and density analysis of the growth and dissociation processes for a variety of hydrates besides THF hydrates.
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title Imaging and density mapping of tetrahydrofuran clathrate hydratesby phase-contrast x-ray computed tomography
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