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Synthesis and characterisation of diorganotin(IV) complexes of 3,4-dihydroxybenzaldehyde semicarbazone

The diorganotin(IV) complexes of the type Me2SnL, Bu2SnL and Ph2SnL (L) with the anion of the semicarbazone ligand formed by condensation reaction of 3,4-dihydroxybenzaldehyde with semicarbazide were synthesized using 1:1 metal to ligand reactant ratios. The newly synthesized complexes were characte...

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Main Authors:	Hussien, Nasry Jassim, Farina, Yang, Al-Jeboori, Mohamad Jaber
Format:	Conference Proceeding
Language:	English
Subjects:	Anions Chelation Chemical synthesis Complex formation Infrared analysis Ligands NMR Nuclear magnetic resonance
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creator	Hussien, Nasry Jassim Farina, Yang Al-Jeboori, Mohamad Jaber
description	The diorganotin(IV) complexes of the type Me2SnL, Bu2SnL and Ph2SnL (L) with the anion of the semicarbazone ligand formed by condensation reaction of 3,4-dihydroxybenzaldehyde with semicarbazide were synthesized using 1:1 metal to ligand reactant ratios. The newly synthesized complexes were characterized using elemental analysis, infrared and nuclear magnetic resonance (1H, 13C,119Sn) spectroscopic techniques. Complex formation between the organotin(IV) moiety and the anion of 3,4-dihydroxybenzaldehysemicarbazone occurred with chelation at the o-dihydroxy positions. The complexes were proposed to have tetrahedral geometry.
doi_str_mv	10.1063/1.4966744
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source	American Institute of Physics:Jisc Collections:Transitional Journals Agreement 2021-23 (Reading list)
subjects	Anions Chelation Chemical synthesis Complex formation Infrared analysis Ligands NMR Nuclear magnetic resonance
title	Synthesis and characterisation of diorganotin(IV) complexes of 3,4-dihydroxybenzaldehyde semicarbazone
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