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Enhanced kinetic stability of a bulk metallic glass by high pressure

The metastable nature of metallic glasses (MGs) limits their applications. We report the formation of a stable Pd40.16Ni9.64Cu30.12P20.08 MG with bulk size under high pressure at room temperature. The stable MG shows remarkably enhanced thermal and kinetic stability with substantially increased glas...

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Bibliographic Details
Published in:Applied physics letters 2016-11, Vol.109 (22)
Main Authors: Xue, R. J., Zhao, L. Z., Shi, C. L., Ma, T., Xi, X. K., Gao, M., Zhu, P. W., Wen, P., Yu, X. H., Jin, C. Q., Pan, M. X., Wang, W. H., Bai, H. Y.
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Language:English
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Summary:The metastable nature of metallic glasses (MGs) limits their applications. We report the formation of a stable Pd40.16Ni9.64Cu30.12P20.08 MG with bulk size under high pressure at room temperature. The stable MG shows remarkably enhanced thermal and kinetic stability with substantially increased glass transition temperature T g, crystallization temperature T x, density and mechanical properties. The unique stability can be further reinforced by higher pressure and maintained even above T g. This result can advance the glass design and the understanding of the fundamental issues in MGs.
ISSN:0003-6951
1077-3118
DOI:10.1063/1.4968834