Raman studies of Ball mill synthesized bulk Cu2ZnSnSe4

Kesterite with chemical formula Cu2ZnSnSe4 (CZTSe) has been synthesized by ball milling followed by annealing and hot pressing. Mechanochemical synthesis was carried out in the presence of process control agent namely toluene under two different milling conditions. Structural and phase evolution dur...

Full description

Saved in:
Bibliographic Details
Main Authors: Tiwari, Kunal J., S., Prem Kumar D., Mallik, Ramesh Chandra, Malar, P.
Format: Conference Proceeding
Language:English
Citations: Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c265t-56242cafd04ab9c93074464bfa70514f95228159804fb0cb386942c23896bcbf3
cites
container_end_page
container_issue 1
container_start_page
container_title
container_volume 1832
creator Tiwari, Kunal J.
S., Prem Kumar D.
Mallik, Ramesh Chandra
Malar, P.
description Kesterite with chemical formula Cu2ZnSnSe4 (CZTSe) has been synthesized by ball milling followed by annealing and hot pressing. Mechanochemical synthesis was carried out in the presence of process control agent namely toluene under two different milling conditions. Structural and phase evolution during different stages of the synthesis was studied with X-ray diffraction (XRD) and Raman spectroscopy. Near resonant Raman spectrum was obtained by making use of laser wavelength of 488 nm to resolve the presence of secondary ZnSe which otherwise is difficult to conclude with XRD alone. Deconvoluted Raman spectrum confirmed the presence of CZTSe along with secondary phases Cu2SnSe3 (CTSe) and ZnSe. This inference was further confirmed by electron probe micro analysis (EPMA) and wavelength dispersive spectroscopy (WDS) studies.
doi_str_mv 10.1063/1.4980424
format conference_proceeding
fullrecord <record><control><sourceid>scitation</sourceid><recordid>TN_cdi_scitation_primary_10_1063_1_4980424</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>acp</sourcerecordid><originalsourceid>FETCH-LOGICAL-c265t-56242cafd04ab9c93074464bfa70514f95228159804fb0cb386942c23896bcbf3</originalsourceid><addsrcrecordid>eNp9UEtLxDAYDKJgXT34D3IWun5JvqTNUYsvWBBcBfESkrTBaB9L0xXWX-8uLnjzMnOZGWaGkHMGcwZKXLI56hKQ4wHJmJQsLxRThyQD0JhzFK_H5CSlDwCui6LMiHqyne1pmtZ1bBIdAr22bUu7uIW06af3JsXvpqZu3X7Sas3f-mW_bPCUHAXbpuZszzPycnvzXN3ni8e7h-pqkXuu5JRLxZF7G2pA67TXAgpEhS7YAiTDoCXnJZO7xsGBd6JUemvgotTKeRfEjFz85iYfJzvFoTerMXZ23JivYTTM7NeaVf2vmIHZ3fNnED811VUm</addsrcrecordid><sourcetype>Enrichment Source</sourcetype><iscdi>true</iscdi><recordtype>conference_proceeding</recordtype></control><display><type>conference_proceeding</type><title>Raman studies of Ball mill synthesized bulk Cu2ZnSnSe4</title><source>American Institute of Physics:Jisc Collections:Transitional Journals Agreement 2021-23 (Reading list)</source><creator>Tiwari, Kunal J. ; S., Prem Kumar D. ; Mallik, Ramesh Chandra ; Malar, P.</creator><contributor>Das, Amitabh ; Singh, Surendra ; Bhattacharya, Shovit ; Basu, Saibal</contributor><creatorcontrib>Tiwari, Kunal J. ; S., Prem Kumar D. ; Mallik, Ramesh Chandra ; Malar, P. ; Das, Amitabh ; Singh, Surendra ; Bhattacharya, Shovit ; Basu, Saibal</creatorcontrib><description>Kesterite with chemical formula Cu2ZnSnSe4 (CZTSe) has been synthesized by ball milling followed by annealing and hot pressing. Mechanochemical synthesis was carried out in the presence of process control agent namely toluene under two different milling conditions. Structural and phase evolution during different stages of the synthesis was studied with X-ray diffraction (XRD) and Raman spectroscopy. Near resonant Raman spectrum was obtained by making use of laser wavelength of 488 nm to resolve the presence of secondary ZnSe which otherwise is difficult to conclude with XRD alone. Deconvoluted Raman spectrum confirmed the presence of CZTSe along with secondary phases Cu2SnSe3 (CTSe) and ZnSe. This inference was further confirmed by electron probe micro analysis (EPMA) and wavelength dispersive spectroscopy (WDS) studies.</description><identifier>ISSN: 0094-243X</identifier><identifier>EISSN: 1551-7616</identifier><identifier>DOI: 10.1063/1.4980424</identifier><identifier>CODEN: APCPCS</identifier><language>eng</language><ispartof>AIP conference proceedings, 2017, Vol.1832 (1)</ispartof><rights>Author(s)</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c265t-56242cafd04ab9c93074464bfa70514f95228159804fb0cb386942c23896bcbf3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><contributor>Das, Amitabh</contributor><contributor>Singh, Surendra</contributor><contributor>Bhattacharya, Shovit</contributor><contributor>Basu, Saibal</contributor><creatorcontrib>Tiwari, Kunal J.</creatorcontrib><creatorcontrib>S., Prem Kumar D.</creatorcontrib><creatorcontrib>Mallik, Ramesh Chandra</creatorcontrib><creatorcontrib>Malar, P.</creatorcontrib><title>Raman studies of Ball mill synthesized bulk Cu2ZnSnSe4</title><title>AIP conference proceedings</title><description>Kesterite with chemical formula Cu2ZnSnSe4 (CZTSe) has been synthesized by ball milling followed by annealing and hot pressing. Mechanochemical synthesis was carried out in the presence of process control agent namely toluene under two different milling conditions. Structural and phase evolution during different stages of the synthesis was studied with X-ray diffraction (XRD) and Raman spectroscopy. Near resonant Raman spectrum was obtained by making use of laser wavelength of 488 nm to resolve the presence of secondary ZnSe which otherwise is difficult to conclude with XRD alone. Deconvoluted Raman spectrum confirmed the presence of CZTSe along with secondary phases Cu2SnSe3 (CTSe) and ZnSe. This inference was further confirmed by electron probe micro analysis (EPMA) and wavelength dispersive spectroscopy (WDS) studies.</description><issn>0094-243X</issn><issn>1551-7616</issn><fulltext>true</fulltext><rsrctype>conference_proceeding</rsrctype><creationdate>2017</creationdate><recordtype>conference_proceeding</recordtype><sourceid/><recordid>eNp9UEtLxDAYDKJgXT34D3IWun5JvqTNUYsvWBBcBfESkrTBaB9L0xXWX-8uLnjzMnOZGWaGkHMGcwZKXLI56hKQ4wHJmJQsLxRThyQD0JhzFK_H5CSlDwCui6LMiHqyne1pmtZ1bBIdAr22bUu7uIW06af3JsXvpqZu3X7Sas3f-mW_bPCUHAXbpuZszzPycnvzXN3ni8e7h-pqkXuu5JRLxZF7G2pA67TXAgpEhS7YAiTDoCXnJZO7xsGBd6JUemvgotTKeRfEjFz85iYfJzvFoTerMXZ23JivYTTM7NeaVf2vmIHZ3fNnED811VUm</recordid><startdate>20170519</startdate><enddate>20170519</enddate><creator>Tiwari, Kunal J.</creator><creator>S., Prem Kumar D.</creator><creator>Mallik, Ramesh Chandra</creator><creator>Malar, P.</creator><scope/></search><sort><creationdate>20170519</creationdate><title>Raman studies of Ball mill synthesized bulk Cu2ZnSnSe4</title><author>Tiwari, Kunal J. ; S., Prem Kumar D. ; Mallik, Ramesh Chandra ; Malar, P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c265t-56242cafd04ab9c93074464bfa70514f95228159804fb0cb386942c23896bcbf3</frbrgroupid><rsrctype>conference_proceedings</rsrctype><prefilter>conference_proceedings</prefilter><language>eng</language><creationdate>2017</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tiwari, Kunal J.</creatorcontrib><creatorcontrib>S., Prem Kumar D.</creatorcontrib><creatorcontrib>Mallik, Ramesh Chandra</creatorcontrib><creatorcontrib>Malar, P.</creatorcontrib></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tiwari, Kunal J.</au><au>S., Prem Kumar D.</au><au>Mallik, Ramesh Chandra</au><au>Malar, P.</au><au>Das, Amitabh</au><au>Singh, Surendra</au><au>Bhattacharya, Shovit</au><au>Basu, Saibal</au><format>book</format><genre>proceeding</genre><ristype>CONF</ristype><atitle>Raman studies of Ball mill synthesized bulk Cu2ZnSnSe4</atitle><btitle>AIP conference proceedings</btitle><date>2017-05-19</date><risdate>2017</risdate><volume>1832</volume><issue>1</issue><issn>0094-243X</issn><eissn>1551-7616</eissn><coden>APCPCS</coden><abstract>Kesterite with chemical formula Cu2ZnSnSe4 (CZTSe) has been synthesized by ball milling followed by annealing and hot pressing. Mechanochemical synthesis was carried out in the presence of process control agent namely toluene under two different milling conditions. Structural and phase evolution during different stages of the synthesis was studied with X-ray diffraction (XRD) and Raman spectroscopy. Near resonant Raman spectrum was obtained by making use of laser wavelength of 488 nm to resolve the presence of secondary ZnSe which otherwise is difficult to conclude with XRD alone. Deconvoluted Raman spectrum confirmed the presence of CZTSe along with secondary phases Cu2SnSe3 (CTSe) and ZnSe. This inference was further confirmed by electron probe micro analysis (EPMA) and wavelength dispersive spectroscopy (WDS) studies.</abstract><doi>10.1063/1.4980424</doi><tpages>3</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0094-243X
ispartof AIP conference proceedings, 2017, Vol.1832 (1)
issn 0094-243X
1551-7616
language eng
recordid cdi_scitation_primary_10_1063_1_4980424
source American Institute of Physics:Jisc Collections:Transitional Journals Agreement 2021-23 (Reading list)
title Raman studies of Ball mill synthesized bulk Cu2ZnSnSe4
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-01T00%3A18%3A41IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-scitation&rft_val_fmt=info:ofi/fmt:kev:mtx:book&rft.genre=proceeding&rft.atitle=Raman%20studies%20of%20Ball%20mill%20synthesized%20bulk%20Cu2ZnSnSe4&rft.btitle=AIP%20conference%20proceedings&rft.au=Tiwari,%20Kunal%20J.&rft.date=2017-05-19&rft.volume=1832&rft.issue=1&rft.issn=0094-243X&rft.eissn=1551-7616&rft.coden=APCPCS&rft_id=info:doi/10.1063/1.4980424&rft_dat=%3Cscitation%3Eacp%3C/scitation%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c265t-56242cafd04ab9c93074464bfa70514f95228159804fb0cb386942c23896bcbf3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true