Synthesis and properties of polynorbornenes containing trialkoxysilyl groups

In this work we report the synthesis and polymerization of new norbornenes containing trialkoxysilyl groups. These monomers were reactive both in ROMP and in addition polymerization. Obtained polymers possessed interesting properties. So despite of low surface area they were good permeable, and some...

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Bibliographic Details
Main Authors: Alentiev, Dmitry A., Bermeshev, Maxim V., Starannikova, Lyudmila E., Yampolskii, Yuri P., Krut’ko, Ekaterina B., Asachenko, Andrey F., Gribanov, Pavel S., Topchiy, Maxim A., Nechaev, Mikhail S., Finkelshtein, Eugene Sh
Format: Conference Proceeding
Language:English
Subjects:
Addition polymerization
Chemical synthesis
Gas membrane separation
Hydrocarbons
Industrial applications
Polymerization
Polymers
Polynorbornene
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Summary:In this work we report the synthesis and polymerization of new norbornenes containing trialkoxysilyl groups. These monomers were reactive both in ROMP and in addition polymerization. Obtained polymers possessed interesting properties. So despite of low surface area they were good permeable, and some of them exhibited a low tendency to aging. The solubility controlled selectivity for hydrocarbons was observed. These properties would allow finding industrial application of obtained polymers for the membrane gas separation of hydrocarbon mixtures.
ISSN:0094-243X
1551-7616
DOI:10.1063/1.5046030