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Synthesis and properties of polynorbornenes containing trialkoxysilyl groups

In this work we report the synthesis and polymerization of new norbornenes containing trialkoxysilyl groups. These monomers were reactive both in ROMP and in addition polymerization. Obtained polymers possessed interesting properties. So despite of low surface area they were good permeable, and some...

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Main Authors: Alentiev, Dmitry A., Bermeshev, Maxim V., Starannikova, Lyudmila E., Yampolskii, Yuri P., Krut’ko, Ekaterina B., Asachenko, Andrey F., Gribanov, Pavel S., Topchiy, Maxim A., Nechaev, Mikhail S., Finkelshtein, Eugene Sh
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container_volume 1981
creator Alentiev, Dmitry A.
Bermeshev, Maxim V.
Starannikova, Lyudmila E.
Yampolskii, Yuri P.
Krut’ko, Ekaterina B.
Asachenko, Andrey F.
Gribanov, Pavel S.
Topchiy, Maxim A.
Nechaev, Mikhail S.
Finkelshtein, Eugene Sh
description In this work we report the synthesis and polymerization of new norbornenes containing trialkoxysilyl groups. These monomers were reactive both in ROMP and in addition polymerization. Obtained polymers possessed interesting properties. So despite of low surface area they were good permeable, and some of them exhibited a low tendency to aging. The solubility controlled selectivity for hydrocarbons was observed. These properties would allow finding industrial application of obtained polymers for the membrane gas separation of hydrocarbon mixtures.
doi_str_mv 10.1063/1.5046030
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source American Institute of Physics:Jisc Collections:Transitional Journals Agreement 2021-23 (Reading list)
subjects Addition polymerization
Chemical synthesis
Gas membrane separation
Hydrocarbons
Industrial applications
Polymerization
Polymers
Polynorbornene
title Synthesis and properties of polynorbornenes containing trialkoxysilyl groups
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