A monitoring of the kinetics thermally degradation selected rubber by electrical methods

The work presents the possibilities of diagnostics of irreversible chemical reaction – thermal degradation in case of industry prepared rubber mixture based on styrene - butadiene (SBR) using measurements of selected physical parameters. Our attention was focused on the measurement of electrical par...

Full description

Saved in:
Bibliographic Details
Main Authors: Bošák, Ondrej, Preťo, Jozef, Minárik, Stanislav, Kubliha, Marian, Rusnáková, Soňa, Hronkovič, Ján, Labaš, Vladimír
Format: Conference Proceeding
Language:English
Subjects:
Approximation
Butadiene
Chemical reactions
Differential equations
Electrical properties
Electrical resistivity
Frequency ranges
Mathematical analysis
Monitoring
Organic chemistry
Parameters
Physical properties
Reaction kinetics
Rubber
Temperature dependence
Thermal degradation
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page
container_issue 1
container_start_page
container_title
container_volume 2071
creator Bošák, Ondrej
Preťo, Jozef
Minárik, Stanislav
Kubliha, Marian
Rusnáková, Soňa
Hronkovič, Ján
Labaš, Vladimír
description The work presents the possibilities of diagnostics of irreversible chemical reaction – thermal degradation in case of industry prepared rubber mixture based on styrene - butadiene (SBR) using measurements of selected physical parameters. Our attention was focused on the measurement of electrical parameters (electrical conductivity). Procedure of the measurement of electrical properties was applied at the constant temperatures from the range 150 °C to 200 °C. The determination of electrical properties by means of the measurements of time dependencies of alternate conductivity (σAC=σ(t)), were performed in frequency range 20Hz - 100kHz. It is possible describe significant constants of the kinetics of degradation reaction (reaction rate coefficient) by the solution of differential equations and by mathematical approximation. The constants are exponentially dependent on the temperature of thermal degradation. In addition the approximation allows describe the thermal degradation in the temperature range outside of the monitoring interval.
doi_str_mv 10.1063/1.5090066
format conference_proceeding
fullrecord <record><control><sourceid>proquest_scita</sourceid><recordid>TN_cdi_scitation_primary_10_1063_1_5090066</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2173189738</sourcerecordid><originalsourceid>FETCH-LOGICAL-p253t-6238408e028d5e24544a18f744405e7e3aba265b3e7952d8a8ecae68022f654e3</originalsourceid><addsrcrecordid>eNp9kEtLAzEUhYMoWKsL_0HAnTA172SWpfiCghuF7kJm5k6bOp2MSSr039uH4M7V5Vy-cy_nIHRLyYQSxR_oRJKSEKXO0IhKSQutqDpHI0JKUTDBF5foKqU1IazU2ozQYoo3ofc5RN8vcWhxXgH-9D1kX6eDiBvXdTvcwDK6xmUfepyggzpDg-O2qiDiaoePm-hr1-EN5FVo0jW6aF2X4OZ3jtHH0-P77KWYvz2_zqbzYmCS50IxbgQxQJhpJDAhhXDUtFoIQSRo4K5yTMmKgy4la4wzUDtQhjDWKimAj9Hd6e4Qw9cWUrbrsI39_qVlVHNqSs3Nnro_Uan2-ZjCDtFvXNzZ7xAttb-t2aFp_4MpsYea_wz8B0Iybsg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>conference_proceeding</recordtype><pqid>2173189738</pqid></control><display><type>conference_proceeding</type><title>A monitoring of the kinetics thermally degradation selected rubber by electrical methods</title><source>American Institute of Physics:Jisc Collections:Transitional Journals Agreement 2021-23 (Reading list)</source><creator>Bošák, Ondrej ; Preťo, Jozef ; Minárik, Stanislav ; Kubliha, Marian ; Rusnáková, Soňa ; Hronkovič, Ján ; Labaš, Vladimír</creator><contributor>Marin, Catalin Nicolae</contributor><creatorcontrib>Bošák, Ondrej ; Preťo, Jozef ; Minárik, Stanislav ; Kubliha, Marian ; Rusnáková, Soňa ; Hronkovič, Ján ; Labaš, Vladimír ; Marin, Catalin Nicolae</creatorcontrib><description>The work presents the possibilities of diagnostics of irreversible chemical reaction – thermal degradation in case of industry prepared rubber mixture based on styrene - butadiene (SBR) using measurements of selected physical parameters. Our attention was focused on the measurement of electrical parameters (electrical conductivity). Procedure of the measurement of electrical properties was applied at the constant temperatures from the range 150 °C to 200 °C. The determination of electrical properties by means of the measurements of time dependencies of alternate conductivity (σAC=σ(t)), were performed in frequency range 20Hz - 100kHz. It is possible describe significant constants of the kinetics of degradation reaction (reaction rate coefficient) by the solution of differential equations and by mathematical approximation. The constants are exponentially dependent on the temperature of thermal degradation. In addition the approximation allows describe the thermal degradation in the temperature range outside of the monitoring interval.</description><identifier>ISSN: 0094-243X</identifier><identifier>EISSN: 1551-7616</identifier><identifier>DOI: 10.1063/1.5090066</identifier><identifier>CODEN: APCPCS</identifier><language>eng</language><publisher>Melville: American Institute of Physics</publisher><subject>Approximation ; Butadiene ; Chemical reactions ; Differential equations ; Electrical properties ; Electrical resistivity ; Frequency ranges ; Mathematical analysis ; Monitoring ; Organic chemistry ; Parameters ; Physical properties ; Reaction kinetics ; Rubber ; Temperature dependence ; Thermal degradation</subject><ispartof>AIP conference proceedings, 2019, Vol.2071 (1)</ispartof><rights>Author(s)</rights><rights>2019 Author(s). Published by AIP Publishing.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>309,310,314,778,782,787,788,23917,23918,25127,27911,27912</link.rule.ids></links><search><contributor>Marin, Catalin Nicolae</contributor><creatorcontrib>Bošák, Ondrej</creatorcontrib><creatorcontrib>Preťo, Jozef</creatorcontrib><creatorcontrib>Minárik, Stanislav</creatorcontrib><creatorcontrib>Kubliha, Marian</creatorcontrib><creatorcontrib>Rusnáková, Soňa</creatorcontrib><creatorcontrib>Hronkovič, Ján</creatorcontrib><creatorcontrib>Labaš, Vladimír</creatorcontrib><title>A monitoring of the kinetics thermally degradation selected rubber by electrical methods</title><title>AIP conference proceedings</title><description>The work presents the possibilities of diagnostics of irreversible chemical reaction – thermal degradation in case of industry prepared rubber mixture based on styrene - butadiene (SBR) using measurements of selected physical parameters. Our attention was focused on the measurement of electrical parameters (electrical conductivity). Procedure of the measurement of electrical properties was applied at the constant temperatures from the range 150 °C to 200 °C. The determination of electrical properties by means of the measurements of time dependencies of alternate conductivity (σAC=σ(t)), were performed in frequency range 20Hz - 100kHz. It is possible describe significant constants of the kinetics of degradation reaction (reaction rate coefficient) by the solution of differential equations and by mathematical approximation. The constants are exponentially dependent on the temperature of thermal degradation. In addition the approximation allows describe the thermal degradation in the temperature range outside of the monitoring interval.</description><subject>Approximation</subject><subject>Butadiene</subject><subject>Chemical reactions</subject><subject>Differential equations</subject><subject>Electrical properties</subject><subject>Electrical resistivity</subject><subject>Frequency ranges</subject><subject>Mathematical analysis</subject><subject>Monitoring</subject><subject>Organic chemistry</subject><subject>Parameters</subject><subject>Physical properties</subject><subject>Reaction kinetics</subject><subject>Rubber</subject><subject>Temperature dependence</subject><subject>Thermal degradation</subject><issn>0094-243X</issn><issn>1551-7616</issn><fulltext>true</fulltext><rsrctype>conference_proceeding</rsrctype><creationdate>2019</creationdate><recordtype>conference_proceeding</recordtype><recordid>eNp9kEtLAzEUhYMoWKsL_0HAnTA172SWpfiCghuF7kJm5k6bOp2MSSr039uH4M7V5Vy-cy_nIHRLyYQSxR_oRJKSEKXO0IhKSQutqDpHI0JKUTDBF5foKqU1IazU2ozQYoo3ofc5RN8vcWhxXgH-9D1kX6eDiBvXdTvcwDK6xmUfepyggzpDg-O2qiDiaoePm-hr1-EN5FVo0jW6aF2X4OZ3jtHH0-P77KWYvz2_zqbzYmCS50IxbgQxQJhpJDAhhXDUtFoIQSRo4K5yTMmKgy4la4wzUDtQhjDWKimAj9Hd6e4Qw9cWUrbrsI39_qVlVHNqSs3Nnro_Uan2-ZjCDtFvXNzZ7xAttb-t2aFp_4MpsYea_wz8B0Iybsg</recordid><startdate>20190130</startdate><enddate>20190130</enddate><creator>Bošák, Ondrej</creator><creator>Preťo, Jozef</creator><creator>Minárik, Stanislav</creator><creator>Kubliha, Marian</creator><creator>Rusnáková, Soňa</creator><creator>Hronkovič, Ján</creator><creator>Labaš, Vladimír</creator><general>American Institute of Physics</general><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope></search><sort><creationdate>20190130</creationdate><title>A monitoring of the kinetics thermally degradation selected rubber by electrical methods</title><author>Bošák, Ondrej ; Preťo, Jozef ; Minárik, Stanislav ; Kubliha, Marian ; Rusnáková, Soňa ; Hronkovič, Ján ; Labaš, Vladimír</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p253t-6238408e028d5e24544a18f744405e7e3aba265b3e7952d8a8ecae68022f654e3</frbrgroupid><rsrctype>conference_proceedings</rsrctype><prefilter>conference_proceedings</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Approximation</topic><topic>Butadiene</topic><topic>Chemical reactions</topic><topic>Differential equations</topic><topic>Electrical properties</topic><topic>Electrical resistivity</topic><topic>Frequency ranges</topic><topic>Mathematical analysis</topic><topic>Monitoring</topic><topic>Organic chemistry</topic><topic>Parameters</topic><topic>Physical properties</topic><topic>Reaction kinetics</topic><topic>Rubber</topic><topic>Temperature dependence</topic><topic>Thermal degradation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bošák, Ondrej</creatorcontrib><creatorcontrib>Preťo, Jozef</creatorcontrib><creatorcontrib>Minárik, Stanislav</creatorcontrib><creatorcontrib>Kubliha, Marian</creatorcontrib><creatorcontrib>Rusnáková, Soňa</creatorcontrib><creatorcontrib>Hronkovič, Ján</creatorcontrib><creatorcontrib>Labaš, Vladimír</creatorcontrib><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bošák, Ondrej</au><au>Preťo, Jozef</au><au>Minárik, Stanislav</au><au>Kubliha, Marian</au><au>Rusnáková, Soňa</au><au>Hronkovič, Ján</au><au>Labaš, Vladimír</au><au>Marin, Catalin Nicolae</au><format>book</format><genre>proceeding</genre><ristype>CONF</ristype><atitle>A monitoring of the kinetics thermally degradation selected rubber by electrical methods</atitle><btitle>AIP conference proceedings</btitle><date>2019-01-30</date><risdate>2019</risdate><volume>2071</volume><issue>1</issue><issn>0094-243X</issn><eissn>1551-7616</eissn><coden>APCPCS</coden><abstract>The work presents the possibilities of diagnostics of irreversible chemical reaction – thermal degradation in case of industry prepared rubber mixture based on styrene - butadiene (SBR) using measurements of selected physical parameters. Our attention was focused on the measurement of electrical parameters (electrical conductivity). Procedure of the measurement of electrical properties was applied at the constant temperatures from the range 150 °C to 200 °C. The determination of electrical properties by means of the measurements of time dependencies of alternate conductivity (σAC=σ(t)), were performed in frequency range 20Hz - 100kHz. It is possible describe significant constants of the kinetics of degradation reaction (reaction rate coefficient) by the solution of differential equations and by mathematical approximation. The constants are exponentially dependent on the temperature of thermal degradation. In addition the approximation allows describe the thermal degradation in the temperature range outside of the monitoring interval.</abstract><cop>Melville</cop><pub>American Institute of Physics</pub><doi>10.1063/1.5090066</doi><tpages>6</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0094-243X
ispartof AIP conference proceedings, 2019, Vol.2071 (1)
issn 0094-243X
1551-7616
language eng
recordid cdi_scitation_primary_10_1063_1_5090066
source American Institute of Physics:Jisc Collections:Transitional Journals Agreement 2021-23 (Reading list)
subjects Approximation
Butadiene
Chemical reactions
Differential equations
Electrical properties
Electrical resistivity
Frequency ranges
Mathematical analysis
Monitoring
Organic chemistry
Parameters
Physical properties
Reaction kinetics
Rubber
Temperature dependence
Thermal degradation
title A monitoring of the kinetics thermally degradation selected rubber by electrical methods
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-15T14%3A36%3A03IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_scita&rft_val_fmt=info:ofi/fmt:kev:mtx:book&rft.genre=proceeding&rft.atitle=A%20monitoring%20of%20the%20kinetics%20thermally%20degradation%20selected%20rubber%20by%20electrical%20methods&rft.btitle=AIP%20conference%20proceedings&rft.au=Bo%C5%A1%C3%A1k,%20Ondrej&rft.date=2019-01-30&rft.volume=2071&rft.issue=1&rft.issn=0094-243X&rft.eissn=1551-7616&rft.coden=APCPCS&rft_id=info:doi/10.1063/1.5090066&rft_dat=%3Cproquest_scita%3E2173189738%3C/proquest_scita%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-p253t-6238408e028d5e24544a18f744405e7e3aba265b3e7952d8a8ecae68022f654e3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2173189738&rft_id=info:pmid/&rfr_iscdi=true