Synthesis and spectroscopic investigations of some divalent metal complexes with tetradentate Schiff base ligand

Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II) complexes with (3Z,3'Z)-3,3'-(propane-1,3-diylbis(azaneylylidene))bis(2-methylbutan-2-ol) as Schiff base ligand were readied. Their properties and structures have been investigated on the basis of elemental analysis, magnetic measurement, i...

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Bibliographic Details
Main Authors: Al-Ta'yy, Maher A. M., Al-Wazzan, Zainab Th. A.
Format: Conference Proceeding
Language:English
Subjects:
Cadmium compounds
Coordination compounds
Copper
Electronic spectra
Imines
Infrared analysis
Infrared spectra
Ligands
Magnetic measurement
Mercury compounds
Nickel
Oxygen atoms
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Summary:Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II) complexes with (3Z,3'Z)-3,3'-(propane-1,3-diylbis(azaneylylidene))bis(2-methylbutan-2-ol) as Schiff base ligand were readied. Their properties and structures have been investigated on the basis of elemental analysis, magnetic measurement, infrared, electronic spectra, molar conductance's and 1HNMR for the ligand and cadmium complex. The analytical and spectroscopic studies revealed that the Schiff base behaved as a tetra dentate ligand coordinated to the metal ion through the two azomethine nitrogen and the two alcoholic oxygen atoms with the most probable octahedral complexes.
ISSN:0094-243X
1551-7616
DOI:10.1063/5.0121223