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Synthesis of new members of Pb-based 1222 superconductors containing sulfur: (Pb0.75S0.25)Sr2(RE1.6Ce0.4)Cu2Oz (RE = Sm, Gd, Dy, and Ho)
We have discovered new members of the Pb-based 1222 layered cuprates containing sulfur of (Pb 0.75 S 0.25 )Sr 2 (RE 1.6 Ce 0.4 )Cu 2 O z with RE = Sm, Gd, Dy, and Ho. All the samples are of almost-single 1222 phase. From the ρ – T and χ – T measurements, they are found to be superconductors after an...
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Published in: | Journal of materials science. Materials in electronics 2014, Vol.25 (5), p.2183-2187 |
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Main Authors: | , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Online Access: | Get full text |
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Summary: | We have discovered new members of the Pb-based 1222 layered cuprates containing sulfur of (Pb
0.75
S
0.25
)Sr
2
(RE
1.6
Ce
0.4
)Cu
2
O
z
with RE = Sm, Gd, Dy, and Ho. All the samples are of almost-single 1222 phase. From the
ρ
–
T
and
χ
–
T
measurements, they are found to be superconductors after annealing under 125 atm O
2
atmosphere at 400 °C. Among them, the sample with RE = Gd is found to show superconductivity at the highest temperature of 30 K. |
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ISSN: | 0957-4522 1573-482X |
DOI: | 10.1007/s10854-014-1857-7 |