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Negatron effects in CdSe1 − xTex and ZnS1−xSex films

Various negatron effects in films of alloys of II–VI compounds deposited from solutions as a function of the deposition mode and heat treatment are studied. It is found that the negative photocapacitance effect, which was first discovered in ZnS 1− x Se x films, and the slowly relaxing negative phot...

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Published in:Surface investigation, x-ray, synchrotron and neutron techniques x-ray, synchrotron and neutron techniques, 2014, Vol.8 (1), p.131-137
Main Authors: Jafarov, M. A., Nasirov, E. F., Mamedova, S. A., Mekhtiev, R. F.
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container_title Surface investigation, x-ray, synchrotron and neutron techniques
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Nasirov, E. F.
Mamedova, S. A.
Mekhtiev, R. F.
description Various negatron effects in films of alloys of II–VI compounds deposited from solutions as a function of the deposition mode and heat treatment are studied. It is found that the negative photocapacitance effect, which was first discovered in ZnS 1− x Se x films, and the slowly relaxing negative photoelectric effects, which are caused by the transition of electrons located in a nanoscale surface layer from the shallow energy levels of trapping centers to deeper levels with a lower polarizability and by the presence of nanoscale clusters in these materials, which play the role of a “reservoir” for minority charge carriers, occur according to a single mechanism. A model to explain the basic laws of negative photoconductivity in CdSe 1 − x Te x films deposited from a solution is proposed. Negative residual conductivity is explained in terms of double-barrier relief model, while negative differential photoconductivity is attributed to the presence of nanoscale electric domains.
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Surfaces and Interfaces
Thin Films
title Negatron effects in CdSe1 − xTex and ZnS1−xSex films
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