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Nonstoichiometric high-pressure phase of TmxCu3V4O12
Tm x Cu 3 V 4 O 12 , a perovskite-like oxide (space group, Im-3 ; Z = 2; a = 7.279–7.293 Å) containing vacancies in its cationic sublattice, was obtained barothermally ( P = 7.0–9.0 GPa, t = 1000–1100°C) for the first time. The temperature dependences on the electrical resistivity (10–300 K) and the...
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Published in: | Bulletin of the Russian Academy of Sciences. Physics 2011, Vol.75 (8) |
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container_title | Bulletin of the Russian Academy of Sciences. Physics |
container_volume | 75 |
creator | Kadyrova, N. I. Zaynulin, Yu. G. Tyutyunnik, A. P. Melnikova, N. V. Ustinova, I. S. Korolev, A. V. |
description | Tm
x
Cu
3
V
4
O
12
, a perovskite-like oxide (space group,
Im-3
;
Z
= 2;
a
= 7.279–7.293 Å) containing vacancies in its cationic sublattice, was obtained barothermally (
P
= 7.0–9.0 GPa,
t
= 1000–1100°C) for the first time. The temperature dependences on the electrical resistivity (10–300 K) and the magnetic susceptibility (0–300 K) were investigated. It was shown that the oxide Tm
x
Cu
3
V
4
O
12
is characterized by metal-type conductivity and paramagnetic properties. |
doi_str_mv | 10.3103/S1062873811050224 |
format | article |
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x
Cu
3
V
4
O
12
, a perovskite-like oxide (space group,
Im-3
;
Z
= 2;
a
= 7.279–7.293 Å) containing vacancies in its cationic sublattice, was obtained barothermally (
P
= 7.0–9.0 GPa,
t
= 1000–1100°C) for the first time. The temperature dependences on the electrical resistivity (10–300 K) and the magnetic susceptibility (0–300 K) were investigated. It was shown that the oxide Tm
x
Cu
3
V
4
O
12
is characterized by metal-type conductivity and paramagnetic properties.</description><identifier>ISSN: 1062-8738</identifier><identifier>EISSN: 1934-9432</identifier><identifier>DOI: 10.3103/S1062873811050224</identifier><language>eng</language><publisher>Heidelberg: Allerton Press, Inc</publisher><subject>Hadrons ; Heavy Ions ; Nuclear Physics ; Odpo-13 ; Physics ; Physics and Astronomy</subject><ispartof>Bulletin of the Russian Academy of Sciences. Physics, 2011, Vol.75 (8)</ispartof><rights>Allerton Press, Inc. 2011</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids></links><search><creatorcontrib>Kadyrova, N. I.</creatorcontrib><creatorcontrib>Zaynulin, Yu. G.</creatorcontrib><creatorcontrib>Tyutyunnik, A. P.</creatorcontrib><creatorcontrib>Melnikova, N. V.</creatorcontrib><creatorcontrib>Ustinova, I. S.</creatorcontrib><creatorcontrib>Korolev, A. V.</creatorcontrib><title>Nonstoichiometric high-pressure phase of TmxCu3V4O12</title><title>Bulletin of the Russian Academy of Sciences. Physics</title><addtitle>Bull. Russ. Acad. Sci. Phys</addtitle><description>Tm
x
Cu
3
V
4
O
12
, a perovskite-like oxide (space group,
Im-3
;
Z
= 2;
a
= 7.279–7.293 Å) containing vacancies in its cationic sublattice, was obtained barothermally (
P
= 7.0–9.0 GPa,
t
= 1000–1100°C) for the first time. The temperature dependences on the electrical resistivity (10–300 K) and the magnetic susceptibility (0–300 K) were investigated. It was shown that the oxide Tm
x
Cu
3
V
4
O
12
is characterized by metal-type conductivity and paramagnetic properties.</description><subject>Hadrons</subject><subject>Heavy Ions</subject><subject>Nuclear Physics</subject><subject>Odpo-13</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><issn>1062-8738</issn><issn>1934-9432</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqdjrsKwjAYRoMoWC8P4JYXiOaq7VwUJx0srqGUtEmxTcnfgo9vC25uTt8HhwMHoR2je8GoODwYPfL4JGLGqKKcyxmKWCIkSaTg8_GPmEx8iVYANaVKJVxFSN58C713hXW-MX1wBbausqQLBmAIBnc2B4N9ibPmnQ7iKe-Mb9CizF9gtt9dI345Z-mVQBdcW5mgaz-EdkSaUT316Z8-8Zf0AUL8QUs</recordid><startdate>2011</startdate><enddate>2011</enddate><creator>Kadyrova, N. I.</creator><creator>Zaynulin, Yu. G.</creator><creator>Tyutyunnik, A. P.</creator><creator>Melnikova, N. V.</creator><creator>Ustinova, I. S.</creator><creator>Korolev, A. V.</creator><general>Allerton Press, Inc</general><scope/></search><sort><creationdate>2011</creationdate><title>Nonstoichiometric high-pressure phase of TmxCu3V4O12</title><author>Kadyrova, N. I. ; Zaynulin, Yu. G. ; Tyutyunnik, A. P. ; Melnikova, N. V. ; Ustinova, I. S. ; Korolev, A. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-springer_journals_10_3103_S10628738110502243</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Hadrons</topic><topic>Heavy Ions</topic><topic>Nuclear Physics</topic><topic>Odpo-13</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kadyrova, N. I.</creatorcontrib><creatorcontrib>Zaynulin, Yu. G.</creatorcontrib><creatorcontrib>Tyutyunnik, A. P.</creatorcontrib><creatorcontrib>Melnikova, N. V.</creatorcontrib><creatorcontrib>Ustinova, I. S.</creatorcontrib><creatorcontrib>Korolev, A. V.</creatorcontrib><jtitle>Bulletin of the Russian Academy of Sciences. Physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kadyrova, N. I.</au><au>Zaynulin, Yu. G.</au><au>Tyutyunnik, A. P.</au><au>Melnikova, N. V.</au><au>Ustinova, I. S.</au><au>Korolev, A. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Nonstoichiometric high-pressure phase of TmxCu3V4O12</atitle><jtitle>Bulletin of the Russian Academy of Sciences. Physics</jtitle><stitle>Bull. Russ. Acad. Sci. Phys</stitle><date>2011</date><risdate>2011</risdate><volume>75</volume><issue>8</issue><issn>1062-8738</issn><eissn>1934-9432</eissn><abstract>Tm
x
Cu
3
V
4
O
12
, a perovskite-like oxide (space group,
Im-3
;
Z
= 2;
a
= 7.279–7.293 Å) containing vacancies in its cationic sublattice, was obtained barothermally (
P
= 7.0–9.0 GPa,
t
= 1000–1100°C) for the first time. The temperature dependences on the electrical resistivity (10–300 K) and the magnetic susceptibility (0–300 K) were investigated. It was shown that the oxide Tm
x
Cu
3
V
4
O
12
is characterized by metal-type conductivity and paramagnetic properties.</abstract><cop>Heidelberg</cop><pub>Allerton Press, Inc</pub><doi>10.3103/S1062873811050224</doi></addata></record> |
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identifier | ISSN: 1062-8738 |
ispartof | Bulletin of the Russian Academy of Sciences. Physics, 2011, Vol.75 (8) |
issn | 1062-8738 1934-9432 |
language | eng |
recordid | cdi_springer_journals_10_3103_S1062873811050224 |
source | Springer Nature |
subjects | Hadrons Heavy Ions Nuclear Physics Odpo-13 Physics Physics and Astronomy |
title | Nonstoichiometric high-pressure phase of TmxCu3V4O12 |
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