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Nonstoichiometric high-pressure phase of TmxCu3V4O12

Tm x Cu 3 V 4 O 12 , a perovskite-like oxide (space group, Im-3 ; Z = 2; a = 7.279–7.293 Å) containing vacancies in its cationic sublattice, was obtained barothermally ( P = 7.0–9.0 GPa, t = 1000–1100°C) for the first time. The temperature dependences on the electrical resistivity (10–300 K) and the...

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Published in:Bulletin of the Russian Academy of Sciences. Physics 2011, Vol.75 (8)
Main Authors: Kadyrova, N. I., Zaynulin, Yu. G., Tyutyunnik, A. P., Melnikova, N. V., Ustinova, I. S., Korolev, A. V.
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container_title Bulletin of the Russian Academy of Sciences. Physics
container_volume 75
creator Kadyrova, N. I.
Zaynulin, Yu. G.
Tyutyunnik, A. P.
Melnikova, N. V.
Ustinova, I. S.
Korolev, A. V.
description Tm x Cu 3 V 4 O 12 , a perovskite-like oxide (space group, Im-3 ; Z = 2; a = 7.279–7.293 Å) containing vacancies in its cationic sublattice, was obtained barothermally ( P = 7.0–9.0 GPa, t = 1000–1100°C) for the first time. The temperature dependences on the electrical resistivity (10–300 K) and the magnetic susceptibility (0–300 K) were investigated. It was shown that the oxide Tm x Cu 3 V 4 O 12 is characterized by metal-type conductivity and paramagnetic properties.
doi_str_mv 10.3103/S1062873811050224
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G. ; Tyutyunnik, A. P. ; Melnikova, N. V. ; Ustinova, I. S. ; Korolev, A. V.</creatorcontrib><description>Tm x Cu 3 V 4 O 12 , a perovskite-like oxide (space group, Im-3 ; Z = 2; a = 7.279–7.293 Å) containing vacancies in its cationic sublattice, was obtained barothermally ( P = 7.0–9.0 GPa, t = 1000–1100°C) for the first time. The temperature dependences on the electrical resistivity (10–300 K) and the magnetic susceptibility (0–300 K) were investigated. It was shown that the oxide Tm x Cu 3 V 4 O 12 is characterized by metal-type conductivity and paramagnetic properties.</description><identifier>ISSN: 1062-8738</identifier><identifier>EISSN: 1934-9432</identifier><identifier>DOI: 10.3103/S1062873811050224</identifier><language>eng</language><publisher>Heidelberg: Allerton Press, Inc</publisher><subject>Hadrons ; Heavy Ions ; Nuclear Physics ; Odpo-13 ; Physics ; Physics and Astronomy</subject><ispartof>Bulletin of the Russian Academy of Sciences. 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subjects Hadrons
Heavy Ions
Nuclear Physics
Odpo-13
Physics
Physics and Astronomy
title Nonstoichiometric high-pressure phase of TmxCu3V4O12
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