Two-Photon Absorption Circular Dichroism: A New Twist in Nonlinear Spectroscopy

Herein we report on the full experimental measurement of the two‐photon absorption circular dichroism spectra of (S)‐(−)‐1,1′‐bi(2‐naphthol) and (R)‐(+)‐1,1′‐bi(2‐naphthol), their analysis, and theoretical support. The finding of new nonlinear optical fingerprints in chiral molecules offers new oppo...

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Published in:Chemistry : a European journal 2010-03, Vol.16 (11), p.3504-3509
Main Authors: Toro, Carlos, De Boni, Leonardo, Lin, Na, Santoro, Fabrizio, Rizzo, Antonio, Hernandez, Florencio E.
Format: Article
Language:English
Subjects:
Absorption
Chemistry
chirality
Circular Dichroism
Circularity
Dichroism
Fingerprints
Kemi
Naphthols - chemistry
NATURAL SCIENCES
NATURVETENSKAP
Nonlinearity
Optical activity
Photons
Recognition
Spectra
Spectroscopy
Spectrum analysis
Stereoisomerism
Teoretisk kemi
Theoretical chemistry
two-photon absorption
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cited_by cdi_FETCH-LOGICAL-c4486-48641ad648515e89d2a31f1c323ce50397241b1f1a2f3c8119c827324f0b99843
cites cdi_FETCH-LOGICAL-c4486-48641ad648515e89d2a31f1c323ce50397241b1f1a2f3c8119c827324f0b99843
container_end_page 3509
container_issue 11
container_start_page 3504
container_title Chemistry : a European journal
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creator Toro, Carlos
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Lin, Na
Santoro, Fabrizio
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Hernandez, Florencio E.
description Herein we report on the full experimental measurement of the two‐photon absorption circular dichroism spectra of (S)‐(−)‐1,1′‐bi(2‐naphthol) and (R)‐(+)‐1,1′‐bi(2‐naphthol), their analysis, and theoretical support. The finding of new nonlinear optical fingerprints in chiral molecules offers new opportunities in the recognition and understanding of optically active systems in regions where CD could present strong limitations. Rotation does matter! Two‐photon absorption circular dichroism (2PA‐CD) opens new opportunities in the fundamental study of chiral systems and their recognition in regions where CD presents strong limitations.
doi_str_mv 10.1002/chem.200902286
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source Wiley-Blackwell Read & Publish Collection
subjects Absorption
Chemistry
chirality
Circular Dichroism
Circularity
Dichroism
Fingerprints
Kemi
Naphthols - chemistry
NATURAL SCIENCES
NATURVETENSKAP
Nonlinearity
Optical activity
Photons
Recognition
Spectra
Spectroscopy
Spectrum analysis
Stereoisomerism
Teoretisk kemi
Theoretical chemistry
two-photon absorption
title Two-Photon Absorption Circular Dichroism: A New Twist in Nonlinear Spectroscopy
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