Doped ceria–chloride composite electrolyte for intermediate temperature ceramic membrane fuel cells

• Published in: Materials letters 2002-03, Vol.53 (3), p.186-192
• Main Authors: Fu, Q.X, Zhang, W, Peng, R.R, Peng, D.K, Meng, G.Y, Zhu, B
• Format: Article
• Language: English
• Subjects: 500-degrees-c; Applied sciences; Composite electrolyte; conduction; Conductivity; Energy; Energy. Thermal use of fuels; Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc; Exact sciences and technology; Fuel cells; gadolinium-doped ceria (GDC-LiCl-SrCl2); Gadolinium-doped ceria (GDC–LiCl–SrCl 2); Intermediate temperature ceramic membrane fuel cells (IT-CMFCs); lagao3; lanthanum gallate; li2so4; operation; oxide; proton; solid electrolytes
• ISSN: 0167-577X; 1873-4979; 1873-4979
• DOI: 10.1016/S0167-577X(01)00474-8

A kind of oxide–salt composite electrolyte, gadolinium-doped ceria (GDC)–LiCl–SrCl 2, prepared with hot-press technique, shows superior ionic conductivity, which is 2–10 times higher than that of GDC itself at the temperature range of 400–600 °C. More interestingly, not like the GDC electrolyte, which has some extent of electronic conduction under reducing atmosphere, the composite electrolyte is almost a pure ionic conductor, evidenced by the fuel cell's (FC) open circuit voltage (OCV) close to the theoretical one. The fuel cells based on this composite electrolyte show excellent power density output even at temperature as low as 500 °C (240 mW cm −2 ) in spite of the relatively thick electrolyte (0.4 mm). Such high performance, in combination with its low cost in both raw materials and fabrication process, make this kind of composite electrolyte a good candidate electrolyte material for future ultra-low-cost intermediate temperature ceramic membrane fuel cells (IT-CMFCs).