Synthesis, Structure, and Bonding in Polyiodide and Metal Iodide−Iodine Systems

The first comprehensive overview of polyiodide chemistry since the 1970s is presented. Polyiodide compounds exhibit a vast diversity of structures, preferentially of low-dimensional character, with conducting properties ranging from insulators to metals.

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Bibliographic Details
Published in:Chemical reviews 2003-05, Vol.103 (5), p.1649-1684
Main Authors: Svensson, Per H, Kloo, Lars
Format: Article
Language:English
Subjects:
ab-initio calculations
charge-transfer complexes
Chemical elements
molecular-structure
n = 3
photoelectrochemical solar-cells
polyhalide anions
ray crystal-structures
resonance raman-spectrum
triiodide ion
x-ray
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Description
Summary:The first comprehensive overview of polyiodide chemistry since the 1970s is presented. Polyiodide compounds exhibit a vast diversity of structures, preferentially of low-dimensional character, with conducting properties ranging from insulators to metals.
ISSN:0009-2665
1520-6890
1520-6890
DOI:10.1021/cr0204101