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Plasmonic nano-shells: atomistic discrete interactionversusclassic electrodynamics models

Using the extended discrete interaction model and Mie theory, we investigate the tunability of the optical polarizability of small metallic nano-shells. We show that the spectral positions of symmetric and antisymmetric dipolar plasmon resonances vary with the ratio of particle radius to hole radius...

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Bibliographic Details
Published in:Physical chemistry chemical physics : PCCP 2020, Vol.22 (24), p.13467
Main Authors: Zakomirnyi, Vadim, I, Rasskazov, Ilia L., Kragh Sørensen, Lasse, Carney, P. Scott, Rinkevicius, Zilvinas, Ågren, Hans
Format: Article
Language:English
Online Access:Get full text
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Summary:Using the extended discrete interaction model and Mie theory, we investigate the tunability of the optical polarizability of small metallic nano-shells. We show that the spectral positions of symmetric and antisymmetric dipolar plasmon resonances vary with the ratio of particle radius to hole radius in a manner similar to one predicted for uniform metallic nano-shells using a semiclassical approach of two coupled harmonic oscillators. We show that, according to the extended discrete interaction model, the dipolar plasmon resonances are also present for nano-shells in the 2-13 nm size region and show the same functional dependence seen for larger nano-shells. Using previously fitted data from experiment, we can predict the size-dependence of the plasma frequency for nano-shells in the 1-15 nm size region. We find that Mie theory, which utilizes the electron mean free path correction for the permittivity, is not able to reproduce the same functional form of the dipolar modes for the nano-shells of the same sizes.
ISSN:1463-9076
1463-9084
DOI:10.1039/d0cp02248a