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Converting n‑Alkanol to Conjugated Polyenal on Cu(110) Surface at Mild Temperature
Achieving C(sp3)–H activation at a mild temperature is of great importance from both scientific and technologic points of view. Herein, on the basis of the on-surface synthesis strategy, we report the significant reduction of the C(sp3)–H activation barrier, which results in the full C(sp3)–H to...
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| Published in: | The journal of physical chemistry letters 2022-04, Vol.13 (14), p.3276-3282 |
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| Main Authors: | , , , , , , , , , , , , , |
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| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-a383t-97fc3dc7b11479069323c1ed6bf06df04a8803d4ec84cc882578b02b73839d223 |
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| cites | cdi_FETCH-LOGICAL-a383t-97fc3dc7b11479069323c1ed6bf06df04a8803d4ec84cc882578b02b73839d223 |
| container_end_page | 3282 |
| container_issue | 14 |
| container_start_page | 3276 |
| container_title | The journal of physical chemistry letters |
| container_volume | 13 |
| creator | Hao, Zhengming Peng, Guyue Wang, Lina Li, Xuechao Liu, Ye Xu, Chaojie Niu, Kaifeng Ding, Honghe Hu, Jun Zhang, Liang Dong, Bin Zhang, Haiming Zhu, Junfa Chi, Lifeng |
| description | Achieving C(sp3)–H activation at a mild temperature is of great importance from both scientific and technologic points of view. Herein, on the basis of the on-surface synthesis strategy, we report the significant reduction of the C(sp3)–H activation barrier, which results in the full C(sp3)–H to C(sp2)–H transformation of n-alkanol (octacosan-1-ol) at a mild temperature as low as 350 K on the Cu(110) surface, yielding the conjugated polyenal (octacosa-tridecaenal) as the final product. The reaction mechanism is revealed by the combined scanning tunneling microscope, density functional theory, and synchrotron radiation photoemission spectroscopy. |
| doi_str_mv | 10.1021/acs.jpclett.2c00369 |
| format | article |
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| ispartof | The journal of physical chemistry letters, 2022-04, Vol.13 (14), p.3276-3282 |
| issn | 1948-7185 1948-7185 |
| language | eng |
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| source | American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list) |
| subjects | Physical Insights into Chemistry, Catalysis, and Interfaces |
| title | Converting n‑Alkanol to Conjugated Polyenal on Cu(110) Surface at Mild Temperature |
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