Polymer Cookery:  Influence of Polymerization Time and Different Initiation Conditions on Performance of Molecularly Imprinted Polymers

A set of polymers was imprinted with (−)-ephedrine using thermal and UV initiation. The performance of the synthesized materials was studied by HPLC. It was shown that the polymer morphology and enantioselective properties are dependent on the polymerization conditions and time of the reaction. The...

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Published in:Macromolecules 2005-02, Vol.38 (4), p.1410-1414
Main Authors: Piletsky, Sergey A, Mijangos, Irene, Guerreiro, Antonio, Piletska, Elena V, Chianella, Iva, Karim, Kal, Turner, Anthony P. F
Format: Article
Language:English
Subjects:
Applied sciences
Exact sciences and technology
Physicochemistry of polymers
Polymerization
Polymers and radiations
TECHNOLOGY
TEKNIKVETENSKAP
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cited_by cdi_FETCH-LOGICAL-a392t-ab23fa2cf305d68543be8b676da99724da0fe0d4e296403d02ed8abc1102866b3
cites cdi_FETCH-LOGICAL-a392t-ab23fa2cf305d68543be8b676da99724da0fe0d4e296403d02ed8abc1102866b3
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container_title Macromolecules
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creator Piletsky, Sergey A
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description A set of polymers was imprinted with (−)-ephedrine using thermal and UV initiation. The performance of the synthesized materials was studied by HPLC. It was shown that the polymer morphology and enantioselective properties are dependent on the polymerization conditions and time of the reaction. The binding mechanism of synthesized polymers was studied using Van't Hoff analysis. The results of testing strongly indicate that the polymer receptor structure is shaped during the initial phase of polymer gelation. The present study shows the importance of controlling experimental conditions in the MIP synthesis and highlights potential problems expected during scaling up of MIP production.
doi_str_mv 10.1021/ma048021r
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source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects Applied sciences
Exact sciences and technology
Physicochemistry of polymers
Polymerization
Polymers and radiations
TECHNOLOGY
TEKNIKVETENSKAP
title Polymer Cookery:  Influence of Polymerization Time and Different Initiation Conditions on Performance of Molecularly Imprinted Polymers
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