Variation in urban snow quality indicated by three seasonal sampling surveys conducted in Luleå (Sweden) within a span of 27 years

• Published in: Journal of contaminant hydrology 2024-01, Vol.260, p.104286-104286, Article 104286
• Main Authors: Vijayan, A, Österlund, H, Marsalek, J, Viklander, M
• Format: Article
• Language: English
• Subjects: Urban Water Engineering; VA-teknik
• ISSN: 0169-7722; 1873-6009; 1873-6009
• DOI: 10.1016/j.jconhyd.2023.104286

Concentrations of total suspended solids (TSS), trace metals (Cu, Cd, Cr, Zn, Cd, Pb), Na and 16 US EPA priority PAHs in urban snow were studied in the City of Luleå in Northern Sweden. Snow was sampled at six central urban and suburban sites with various traffic intensities, in three sampling surveys (1994-95, 2002-03, 2020-21), repeated for three ages of the urban snow cover of 40, 80, and 120 days, respectively. The older data, from the 1994-95 and 2002-03 surveys, were obtained from the existing literature. The concentrations and mass loads of TSS and most trace metals studied (Zn, Cu, Pb, and Cd) varied with time. TSS, Zn, and Cu showed slightly higher concentrations and mass loads in the 2003 (TSS  = 2300 μg/L, Zn  = 620 μg/L and Cu  = 250 μg/L) and 2021 (TSS  = 1500 μg/L, Zn  = 530 μg/L and Cu  = 220 μg/L) sampling surveys, compared to the 1995 survey (TSS  = 620 μg/L, Zn  = 240 μg/L and Cu  = 97 μg/L). However, no evident trend was observed between the 2003 and 2021 sampling surveys. The highest concentrations of Pb and Cd were observed in snow samples from the 1994-95 sampling survey (Pb  = 570 μg/L, Cd  = 4.6 μg/L). Results indicated higher concentrations of the pollutants studied in the city centre, compared to the residential suburbs, and in areas with heavier traffic, where concentrations of metals correlated well with traffic intensity. Fractionation analysis of trace metals indicated that Zn, Cu and Pb occurred mostly in the particulate-bound phase (>0.45 μm) containing the most of Zn, Cu, and Pb mass, at 80, 84 and 94% of the total, respectively. Over 50% of the dissolved phase of Zn and Cu was in the truly dissolved fraction (