Interface-Strengthened Polyimide/Carbon Nanofibers Nanocomposites with Superior Mechanical and Tribological Properties

• Published in: Macromolecular chemistry and physics 2014-07, Vol.215 (14), p.1407-1414
• Main Authors: Zhu, Jiahua, Mu, Liwen, Chen, Long, Shi, Yijun, Wang, Huaiyuan, Feng, Xin, Lu, Xiaohua
• Format: Article
• Language: English
• Subjects: Applied sciences; Carbon fibers; carbon nanofibers; Composites; Elongation; Exact sciences and technology; Fillers; Forms of application and semi-finished materials; interfaces; Machine Elements; Maskinelement; mechanical and tribological properties; Nanocomposites; Nanofibers; Phosphates; polyimide nanocomposites; Polyimide resins; Polymer industry, paints, wood; Technology of polymers; Thermal properties; Tribology
• ISSN: 1022-1352; 1521-3935; 1521-3935
• DOI: 10.1002/macp.201400194

A self‐assembling molecule, n‐octadecane phosphate, is successfully synthesized and used to modify the surface property of carbon nanofibers (CNFs). Both untreated CNFs (CNFs(u)) and treated CNFs (CNFs(t)) are incorporated in polyimide (PI) as filler to study the interfacial­property‐determined thermal, mechanical, and tribological properties of their corresponding nanocomposites. At room temperature, the mechanical properties of PI/CNFs(t) including elongation‐to‐break, tensile strength, bending strength, and impact strength are remarkably improved by 150%, 29.4%, 26.7%, and 183%, respectively, in comparison with the PI/CNFs(u) composites. At 150 °C, the enhancement of the elongation‐to‐break reaches 250%, while the tensile and flexural‐strength enhancement reduce to 2.8% and 20.4%. In addition, the tribological properties of PI/CNFs(t) composite are also improved due to the better interfacial interaction between the filler and the matrix. Microstructure analysis of the fracture surface directly reveals the better dispersion quality of CNFs(t) in PI and superior interfacial adhesion with the introduced assembling layer. A self‐assembling molecule, n‐octadecane phosphate, is synthesized and demonstrated as an effective interface agent to synergistically improve the mechanical, tribological, and thermal properties of carbon nanofibers/polyimide nanocomposites.