Variation of green liquor dregs from different pulp and paper mills for use in mine waste remediation

• Published in: Environmental science and pollution research international 2019-10, Vol.26 (30), p.31284-31300
• Main Authors: Jia, Yu, Hamberg, Roger, Qureshi, Asif, Mäkitalo, Maria, Maurice, Christian
• Format: Article
• Language: English
• Subjects: Acid neutralization; Applied Geochemistry; Aquatic Pollution; Atmospheric Protection/Air Quality Control/Air Pollution; Beneficiation; Buffering capacity; Buffers; Chemical composition; Dewatering; Drying; Earth and Environmental Science; Ecotoxicology; Environment; Environmental Chemistry; Environmental Health; Environmental Restoration and Remediation - methods; Environmental science; Geoteknik; Hazardous wastes; Heavy metals; Immobilization; Landfills; Manufacturing Industry; Metals, Heavy - analysis; Mine wastes; Mineralogy; Mining; Mining industry; Organic chemistry; Plasticity; Pulp & paper industry; Pulp & paper mills; Remediation; Research Article; Retention capacity; Soil Mechanics; Sulfur; Sulfur - analysis; Sulfur content; Tillämpad geokemi; Waste disposal sites; Waste Products; Waste Water Technology; Water Management; Water Pollution Control; Water retention
• ISSN: 0944-1344; 1614-7499; 1614-7499
• DOI: 10.1007/s11356-019-06180-0

The geotechnical, chemical, and mineralogical properties of green liquor dregs (GLDs) generated as byproducts from five paper mills were investigated to assess their buffering and heavy metal immobilization capacities and their roles as water and oxygen barriers. One type of GLD was further studied to test the effects of the retrieval process and the storage, drying, and hydration of GLD. The high water retention capacity of the GLDs is valuable for limiting O 2 diffusion. Laboratory results showed that the GLDs had hydraulic conductivities of 3.7 × 10 −9 –4.6 × 10 −8 m/s and varied regularly in plasticity. The chemical and mineralogical compositions of the GLDs varied greatly, reflecting the raw material used to produce paper and the process used to retrieve GLDs. Although they had high total heavy metal contents, none of the leached elements from the GLDs (L/S 10 cm 3 /kg) exceeded the European Union’s limits for landfills of non-hazardous waste. The GLDs exhibited high buffering capacities. In a supplementary test, the buffering capacities varied (0.0041–0.0114 M H + /g GLD) over 72 d after acid was added to the GLD. Changing the filtration process did not greatly affect the GLDs’ properties but mainly affected the hydraulic conductivity, total heavy metal contents and sulfur content. Analyzing the storage of GLDs is necessary in the mining industry because remediation measures require large amounts of material over short periods. The buffering capacity of the dried GLD decreased slightly. The effect of dewatering caused by the mixing of 2% Na-lignosulfate with GLD (w/w) was low.