X‑ray and Electron Spectroscopy of Water

Here we present an overview of recent developments of X-ray and electron spectroscopy to probe water at different temperatures. Photon-induced ionization followed by detection of electrons from either the O 1s level or the valence band is the basis of photoelectron spectroscopy. Excitation between t...

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Bibliographic Details
Published in:Chemical reviews 2016-07, Vol.116 (13), p.7551-7569
Main Authors: Fransson, Thomas, Harada, Yoshihisa, Kosugi, Nobuhiro, Besley, Nicholas A, Winter, Bernd, Rehr, John J, Pettersson, Lars G. M, Nilsson, Anders
Format: Article
Language:English
Subjects:
Absorption
Computer simulation
Electron spectroscopy
Electronic structure
Electrons
Hydrogen bonding
Hydrogen bonds
Ionization
Phases
Simulation
Spectrum analysis
X-rays
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Summary:Here we present an overview of recent developments of X-ray and electron spectroscopy to probe water at different temperatures. Photon-induced ionization followed by detection of electrons from either the O 1s level or the valence band is the basis of photoelectron spectroscopy. Excitation between the O 1s and the unoccupied states or occupied states is utilized in X-ray absorption and X-ray emission spectroscopies. These techniques probe the electronic structure of the liquid phase and show sensitivity to the local hydrogen-bonding structure. Both experimental aspects related to the measurements and theoretical simulations to assist in the interpretation are discussed in detail. Different model systems are presented such as the different bulk phases of ice and various adsorbed monolayer structures on metal surfaces.
ISSN:0009-2665
1520-6890
1520-6890
DOI:10.1021/acs.chemrev.5b00672