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Pseudo–Jahn-Teller interaction among electronic resonant states of H 3
We study the electronic resonant states of H 3 with energies above the potential energy surface of the H 3 + ground state. These resonant states are important for the dissociative recombination of H 3 + at higher collision energies, and previous studies have indicated that these resonant states exhi...
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Published in: | Physical review. A 2021-03, Vol.103 (3), Article 032801 |
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Main Authors: | , |
Format: | Article |
Language: | English |
Citations: | Items that this one cites |
Online Access: | Get full text |
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Summary: | We study the electronic resonant states of H 3 with energies above the potential energy surface of the H 3 + ground state. These resonant states are important for the dissociative recombination of H 3 + at higher collision energies, and previous studies have indicated that these resonant states exhibit a triple intersection. We introduce a complex generalization of the pseudo–Jahn-Teller model to describe these resonant states. The potential energies and the autoionization widths of the resonant states are computed with electron scattering calculations using the complex Kohn variational method, and the complex model parameters are extracted by a least-square fit to the results. This treatment results in a non-Hermitian pseudo–Jahn-Teller Hamiltonian describing the system. The nonadiabatic coupling and geometric phase are further calculated and used to characterize the enriched topology of the complex adiabatic potential energy surfaces. |
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ISSN: | 2469-9926 2469-9934 2469-9934 |
DOI: | 10.1103/PhysRevA.103.032801 |