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High thermoelectric performance of reduced lanthanide molybdenum oxides densified by spark plasma sintering

Four highly reduced molybdenum oxides LnMo 8O 14 (Ln = La, Ce, Nd and Sm) containing bicapped Mo 8 clusters were synthesized via solid state reaction followed by spark plasma sintering. The thermoelectric properties were investigated, and NdMo 8O 14 exhibits the best performance with the maximum pow...

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Published in:Journal of alloys and compounds 2010-06, Vol.500 (1), p.22-25
Main Authors: Xu, Jianxiao, Sonne, Monica, Yanangiya, Shun-ichi, Van Nong, Ngo, Pryds, Nini, Nygren, Mats, Kleinke, Holger
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cited_by cdi_FETCH-LOGICAL-c473t-23dbe403cf1e6c58f66c3f12d615e44e7a4ec1372c0d714dea94db11c5114ba13
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container_title Journal of alloys and compounds
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creator Xu, Jianxiao
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Kleinke, Holger
description Four highly reduced molybdenum oxides LnMo 8O 14 (Ln = La, Ce, Nd and Sm) containing bicapped Mo 8 clusters were synthesized via solid state reaction followed by spark plasma sintering. The thermoelectric properties were investigated, and NdMo 8O 14 exhibits the best performance with the maximum power factor of 177 μW/mK 2 at 1000 K. The highest ZT of NdMo 8O 14 was determined to be around 0.1 at 1000 K.
doi_str_mv 10.1016/j.jallcom.2010.03.201
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subjects Alloys
Clusters
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Conductivity phenomena in semiconductors and insulators
Electronic transport in condensed matter
Exact sciences and technology
Lanthanides
Maximum power
Molybdenum oxides
NATURAL SCIENCES
NATURVETENSKAP
Physics
Power factor
Solid state
Spark plasma sintering
Thermal conductivity
Thermoelectric
Thermoelectric and thermomagnetic effects
Thermoelectricity
title High thermoelectric performance of reduced lanthanide molybdenum oxides densified by spark plasma sintering
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