One step towards MnAl-based permanent magnets - Differences in magnetic, and microstructural properties from an intermediate annealing step during synthesis

• Published in: Journal of solid state chemistry 2019-06, Vol.274, p.229-236
• Main Authors: Shafeie, Samrand, Fang, Hailiang, Hedlund, Daniel, Nyberg, Axel, Svedlindh, Peter, Gunnarsson, Klas, Sahlberg, Martin
• Format: Article
• Language: English
• Subjects: High temperature synthesis; Magnetic measurements; microstructure; MnAl; permanent magnet; Permanent magnets; Powder diffraction; rare earth free
• ISSN: 0022-4596; 1095-726X; 1095-726X
• DOI: 10.1016/j.jssc.2019.03.035

The influence of an additional annealing step during synthesis on the preparation of MnAl based permanent magnet alloys has been investigated. Bulk samples of Mn55Al45C2 alloys were synthesized using induction heating through drop synthesis from 1400 °C. Samples produced using cooling directly from 1400 °C (from the melt), and from 1400 °C to an intermediate annealing step at 1200 °C for ∼30 min before cooling were compared with respect to differences in phase purity, microstructure and magnetic properties. We found that the phase purity was significantly enhanced using the route with an intermediate annealing step at 1200 °C. From XRD the relative content of the τ-phase was improved from ∼91 wt% for the sample cooled directly from 1400 °C to ∼95.1–99.5 wt% for the sample exposed to an intermediate annealing step before cooling. Additionally, EBSD, and SEM with EDS indicates a clear difference in the phase composition and differences in the distribution of the magnetic τ-phase and the non-magnetic ε-, β-, and γ2-phases. Magnetic properties also indicate an improvement in saturation magnetization for the sample exposed to the extra annealing step during synthesis. Our results suggest that an intermediate annealing step in the production of MnAl based alloys will provide a simple way of achieving better phase purity and magnetic properties in the bulk alloy. [Display omitted] •The importance of an intermediate step in the synthesis of bulk MnAl permanent magnet alloys to obtain a phase pure material.•The effect of this intermediate step on the magnetic properties.•A new synthesis procedure for high purity τ-phase MnAl.